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catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octahedral coordination geometry with four O atoms from two carboxylate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212257/ https://www.ncbi.nlm.nih.gov/pubmed/22090914 http://dx.doi.org/10.1107/S160053681102856X |
Sumario: | In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octahedral coordination geometry with four O atoms from two carboxylate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal carboxylate groups bind the Zn(II) ions, leading to a chain along the c axis. Adjacent chains are further linked by intermolecular π–π interactions with a shortest centroid–centroid distance of 3.586 (3) Å, forming a two-dimensional supramolecular architecture with (6,3)-network topology. |
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