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catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octahedral coordination geometry with four O atoms from two carboxylate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212257/ https://www.ncbi.nlm.nih.gov/pubmed/22090914 http://dx.doi.org/10.1107/S160053681102856X |
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author | Cai, Xue |
author_facet | Cai, Xue |
author_sort | Cai, Xue |
collection | PubMed |
description | In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octahedral coordination geometry with four O atoms from two carboxylate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal carboxylate groups bind the Zn(II) ions, leading to a chain along the c axis. Adjacent chains are further linked by intermolecular π–π interactions with a shortest centroid–centroid distance of 3.586 (3) Å, forming a two-dimensional supramolecular architecture with (6,3)-network topology. |
format | Online Article Text |
id | pubmed-3212257 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32122572011-11-16 catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] Cai, Xue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octahedral coordination geometry with four O atoms from two carboxylate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal carboxylate groups bind the Zn(II) ions, leading to a chain along the c axis. Adjacent chains are further linked by intermolecular π–π interactions with a shortest centroid–centroid distance of 3.586 (3) Å, forming a two-dimensional supramolecular architecture with (6,3)-network topology. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212257/ /pubmed/22090914 http://dx.doi.org/10.1107/S160053681102856X Text en © Xue Cai 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cai, Xue catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] |
title |
catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] |
title_full |
catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] |
title_fullStr |
catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] |
title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] |
title_short |
catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] |
title_sort | catena-poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212257/ https://www.ncbi.nlm.nih.gov/pubmed/22090914 http://dx.doi.org/10.1107/S160053681102856X |
work_keys_str_mv | AT caixue catenapoly110phenanthrolinezincm22oxydibenzoato |