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catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]

In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octa­hedral coordination geometry with four O atoms from two carboxyl­ate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal...

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Autor principal: Cai, Xue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212257/
https://www.ncbi.nlm.nih.gov/pubmed/22090914
http://dx.doi.org/10.1107/S160053681102856X
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author Cai, Xue
author_facet Cai, Xue
author_sort Cai, Xue
collection PubMed
description In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octa­hedral coordination geometry with four O atoms from two carboxyl­ate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal carboxyl­ate groups bind the Zn(II) ions, leading to a chain along the c axis. Adjacent chains are further linked by inter­molecular π–π inter­actions with a shortest centroid–centroid distance of 3.586 (3) Å, forming a two-dimensional supra­molecular architecture with (6,3)-network topology.
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spelling pubmed-32122572011-11-16 catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato] Cai, Xue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Zn(C(14)H(8)O(5))(C(12)H(8)N(2))](n), the Zn(II) ion is in a distorted octa­hedral coordination geometry with four O atoms from two carboxyl­ate groups in bidentate chelating modes and two N atoms from a 1,10-phenanthroline ligand. The two terminal carboxyl­ate groups bind the Zn(II) ions, leading to a chain along the c axis. Adjacent chains are further linked by inter­molecular π–π inter­actions with a shortest centroid–centroid distance of 3.586 (3) Å, forming a two-dimensional supra­molecular architecture with (6,3)-network topology. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212257/ /pubmed/22090914 http://dx.doi.org/10.1107/S160053681102856X Text en © Xue Cai 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Xue
catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
title catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
title_full catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
title_fullStr catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
title_short catena-Poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
title_sort catena-poly[[(1,10-phenanthroline)zinc]-μ-2,2′-oxydibenzoato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212257/
https://www.ncbi.nlm.nih.gov/pubmed/22090914
http://dx.doi.org/10.1107/S160053681102856X
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