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Tetrakis(μ-4-tert-butylbenzoato)-κ(3) O:O,O′;κ(3) O,O′:O′;κ(4) O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2) O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)]
The reaction of praseodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Pr(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Pr(III) ions are linked by two bridging and two bridging–...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212259/ https://www.ncbi.nlm.nih.gov/pubmed/22090916 http://dx.doi.org/10.1107/S1600536811029667 |
| _version_ | 1782215954574344192 |
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| author | Dai, Jun Pan, Rong-Kun Yang, Juan |
| author_facet | Dai, Jun Pan, Rong-Kun Yang, Juan |
| author_sort | Dai, Jun |
| collection | PubMed |
| description | The reaction of praseodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Pr(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Pr(III) ions are linked by two bridging and two bridging–chelating tBBA ligands, with a Pr⋯Pr separation of 4.0817 (9) Å. Each Pr(III) ion is nine-coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water molecule in a distorted tricapped trigonal–prismatic environment. The complex molecules are linked into infinite chains along the c axis by intermolecular O—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3212259 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32122592011-11-16 Tetrakis(μ-4-tert-butylbenzoato)-κ(3) O:O,O′;κ(3) O,O′:O′;κ(4) O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2) O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)] Dai, Jun Pan, Rong-Kun Yang, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of praseodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Pr(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Pr(III) ions are linked by two bridging and two bridging–chelating tBBA ligands, with a Pr⋯Pr separation of 4.0817 (9) Å. Each Pr(III) ion is nine-coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water molecule in a distorted tricapped trigonal–prismatic environment. The complex molecules are linked into infinite chains along the c axis by intermolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212259/ /pubmed/22090916 http://dx.doi.org/10.1107/S1600536811029667 Text en © Dai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dai, Jun Pan, Rong-Kun Yang, Juan Tetrakis(μ-4-tert-butylbenzoato)-κ(3) O:O,O′;κ(3) O,O′:O′;κ(4) O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2) O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)] |
| title | Tetrakis(μ-4-tert-butylbenzoato)-κ(3)
O:O,O′;κ(3)
O,O′:O′;κ(4)
O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)] |
| title_full | Tetrakis(μ-4-tert-butylbenzoato)-κ(3)
O:O,O′;κ(3)
O,O′:O′;κ(4)
O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)] |
| title_fullStr | Tetrakis(μ-4-tert-butylbenzoato)-κ(3)
O:O,O′;κ(3)
O,O′:O′;κ(4)
O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)] |
| title_full_unstemmed | Tetrakis(μ-4-tert-butylbenzoato)-κ(3)
O:O,O′;κ(3)
O,O′:O′;κ(4)
O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)] |
| title_short | Tetrakis(μ-4-tert-butylbenzoato)-κ(3)
O:O,O′;κ(3)
O,O′:O′;κ(4)
O:O′-bis[aquabis(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)] |
| title_sort | tetrakis(μ-4-tert-butylbenzoato)-κ(3)
o:o,o′;κ(3)
o,o′:o′;κ(4)
o:o′-bis[aquabis(4-tert-butylbenzoato-κ(2)
o,o′)(4-tert-butylbenzoic acid-κo)praseodymium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212259/ https://www.ncbi.nlm.nih.gov/pubmed/22090916 http://dx.doi.org/10.1107/S1600536811029667 |
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