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Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4) O (1),N,N′,O (1′)}cobalt(III) acetonitrile monosolvate
In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·CH(3)CN, the Co(III) ion is six-coordinated in a distorted octahedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water molecule and one C atom from a cyanide group at...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212260/ https://www.ncbi.nlm.nih.gov/pubmed/22090917 http://dx.doi.org/10.1107/S1600536811029461 |
| _version_ | 1782215954807128064 |
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| author | Lin, Yang Li, Guang-Ming Chen, Peng Yan, Peng-Fei Hou, Guang-Feng |
| author_facet | Lin, Yang Li, Guang-Ming Chen, Peng Yan, Peng-Fei Hou, Guang-Feng |
| author_sort | Lin, Yang |
| collection | PubMed |
| description | In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·CH(3)CN, the Co(III) ion is six-coordinated in a distorted octahedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water molecule and one C atom from a cyanide group at the axial positions. O—H⋯O hydrogen bonds connect adjacent complex molecules into dimers. C—H⋯N hydrogen bonds and π–π interactions between the benzene rings [centroid–centroid distances = 3.700 (2) and 3.845 (2) Å] are also present. |
| format | Online Article Text |
| id | pubmed-3212260 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32122602011-11-16 Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4) O (1),N,N′,O (1′)}cobalt(III) acetonitrile monosolvate Lin, Yang Li, Guang-Ming Chen, Peng Yan, Peng-Fei Hou, Guang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·CH(3)CN, the Co(III) ion is six-coordinated in a distorted octahedral environment defined by two N atoms and two O atoms from a salen ligand in the equatorial plane and one O atom from a water molecule and one C atom from a cyanide group at the axial positions. O—H⋯O hydrogen bonds connect adjacent complex molecules into dimers. C—H⋯N hydrogen bonds and π–π interactions between the benzene rings [centroid–centroid distances = 3.700 (2) and 3.845 (2) Å] are also present. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212260/ /pubmed/22090917 http://dx.doi.org/10.1107/S1600536811029461 Text en © Lin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lin, Yang Li, Guang-Ming Chen, Peng Yan, Peng-Fei Hou, Guang-Feng Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4) O (1),N,N′,O (1′)}cobalt(III) acetonitrile monosolvate |
| title | Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(III) acetonitrile monosolvate |
| title_full | Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(III) acetonitrile monosolvate |
| title_fullStr | Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(III) acetonitrile monosolvate |
| title_full_unstemmed | Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(III) acetonitrile monosolvate |
| title_short | Aqua(cyanido-κC){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(III) acetonitrile monosolvate |
| title_sort | aqua(cyanido-κc){6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato-κ(4)
o
(1),n,n′,o
(1′)}cobalt(iii) acetonitrile monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212260/ https://www.ncbi.nlm.nih.gov/pubmed/22090917 http://dx.doi.org/10.1107/S1600536811029461 |
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