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{μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate

The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P—Au—Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol­ecule exhibits a twofold rotation axis.

Detalles Bibliográficos
Autores principales: Kriel, Frederik H., Fernandes, Manuel A., Coates, Judy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212261/
https://www.ncbi.nlm.nih.gov/pubmed/22090918
http://dx.doi.org/10.1107/S1600536811028856
Descripción
Sumario:The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P—Au—Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol­ecule exhibits a twofold rotation axis.