Cargando…

{μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate

The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P—Au—Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol­ecule exhibits a twofold rotation axis.

Detalles Bibliográficos
Autores principales: Kriel, Frederik H., Fernandes, Manuel A., Coates, Judy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212261/
https://www.ncbi.nlm.nih.gov/pubmed/22090918
http://dx.doi.org/10.1107/S1600536811028856
_version_ 1782215955029426176
author Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
author_facet Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
author_sort Kriel, Frederik H.
collection PubMed
description The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P—Au—Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol­ecule exhibits a twofold rotation axis.
format Online
Article
Text
id pubmed-3212261
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32122612011-11-16 {μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate Kriel, Frederik H. Fernandes, Manuel A. Coates, Judy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P—Au—Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol­ecule exhibits a twofold rotation axis. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212261/ /pubmed/22090918 http://dx.doi.org/10.1107/S1600536811028856 Text en © Kriel et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
{μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate
title {μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate
title_full {μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate
title_fullStr {μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate
title_full_unstemmed {μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate
title_short {μ-1,2-Bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate
title_sort {μ-1,2-bis[bis(4-meth­oxy­phen­yl)phosphan­yl]-1,2-dimethyl­hydrazine-κ(2) p:p′}bis­[chloridogold(i)] tetra­hydro­furan disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212261/
https://www.ncbi.nlm.nih.gov/pubmed/22090918
http://dx.doi.org/10.1107/S1600536811028856
work_keys_str_mv AT krielfrederikh m12bisbis4methoxyphenylphosphanyl12dimethylhydrazinek2ppbischloridogolditetrahydrofurandisolvate
AT fernandesmanuela m12bisbis4methoxyphenylphosphanyl12dimethylhydrazinek2ppbischloridogolditetrahydrofurandisolvate
AT coatesjudy m12bisbis4methoxyphenylphosphanyl12dimethylhydrazinek2ppbischloridogolditetrahydrofurandisolvate