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Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)

The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the mol­ecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethyl­nicotinamide ligands, two O atoms from two 4-flu...

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Detalles Bibliográficos
Autores principales: Necefoğlu, Hacali, Özbek, Füreya Elif, Öztürk, Vijdan, Adıgüzel, Vedat, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212262/
https://www.ncbi.nlm.nih.gov/pubmed/22090919
http://dx.doi.org/10.1107/S1600536811029941
Descripción
Sumario:The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the mol­ecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethyl­nicotinamide ligands, two O atoms from two 4-fluoro­benzoate (PFB) ligands and two water mol­ecules in a distorted octa­hedral geometry. In the PFB ligand, the carboxyl­ate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link mol­ecules related by translation along the a axis into chains. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing.