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Diaquabis(N,N′-diethylnicotinamide-κN (1))bis(4-fluorobenzoato-κO)copper(II)
The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the molecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethylnicotinamide ligands, two O atoms from two 4-flu...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212262/ https://www.ncbi.nlm.nih.gov/pubmed/22090919 http://dx.doi.org/10.1107/S1600536811029941 |
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author | Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer |
author_facet | Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer |
author_sort | Necefoğlu, Hacali |
collection | PubMed |
description | The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the molecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethylnicotinamide ligands, two O atoms from two 4-fluorobenzoate (PFB) ligands and two water molecules in a distorted octahedral geometry. In the PFB ligand, the carboxylate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link molecules related by translation along the a axis into chains. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the pyridine rings of neighbouring molecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing. |
format | Online Article Text |
id | pubmed-3212262 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32122622011-11-16 Diaquabis(N,N′-diethylnicotinamide-κN (1))bis(4-fluorobenzoato-κO)copper(II) Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the molecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethylnicotinamide ligands, two O atoms from two 4-fluorobenzoate (PFB) ligands and two water molecules in a distorted octahedral geometry. In the PFB ligand, the carboxylate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link molecules related by translation along the a axis into chains. Weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the pyridine rings of neighbouring molecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212262/ /pubmed/22090919 http://dx.doi.org/10.1107/S1600536811029941 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer Diaquabis(N,N′-diethylnicotinamide-κN (1))bis(4-fluorobenzoato-κO)copper(II) |
title | Diaquabis(N,N′-diethylnicotinamide-κN
(1))bis(4-fluorobenzoato-κO)copper(II) |
title_full | Diaquabis(N,N′-diethylnicotinamide-κN
(1))bis(4-fluorobenzoato-κO)copper(II) |
title_fullStr | Diaquabis(N,N′-diethylnicotinamide-κN
(1))bis(4-fluorobenzoato-κO)copper(II) |
title_full_unstemmed | Diaquabis(N,N′-diethylnicotinamide-κN
(1))bis(4-fluorobenzoato-κO)copper(II) |
title_short | Diaquabis(N,N′-diethylnicotinamide-κN
(1))bis(4-fluorobenzoato-κO)copper(II) |
title_sort | diaquabis(n,n′-diethylnicotinamide-κn
(1))bis(4-fluorobenzoato-κo)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212262/ https://www.ncbi.nlm.nih.gov/pubmed/22090919 http://dx.doi.org/10.1107/S1600536811029941 |
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