Cargando…

Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)

The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the mol­ecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethyl­nicotinamide ligands, two O atoms from two 4-flu...

Descripción completa

Detalles Bibliográficos
Autores principales: Necefoğlu, Hacali, Özbek, Füreya Elif, Öztürk, Vijdan, Adıgüzel, Vedat, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212262/
https://www.ncbi.nlm.nih.gov/pubmed/22090919
http://dx.doi.org/10.1107/S1600536811029941
_version_ 1782215955250675712
author Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the mol­ecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethyl­nicotinamide ligands, two O atoms from two 4-fluoro­benzoate (PFB) ligands and two water mol­ecules in a distorted octa­hedral geometry. In the PFB ligand, the carboxyl­ate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link mol­ecules related by translation along the a axis into chains. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing.
format Online
Article
Text
id pubmed-3212262
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32122622011-11-16 Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II) Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains one-half of the mol­ecule. The Cu(II) ion is located on an inversion centre, and is coordinated by two N atoms from two diethyl­nicotinamide ligands, two O atoms from two 4-fluoro­benzoate (PFB) ligands and two water mol­ecules in a distorted octa­hedral geometry. In the PFB ligand, the carboxyl­ate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link mol­ecules related by translation along the a axis into chains. Weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3212262/ /pubmed/22090919 http://dx.doi.org/10.1107/S1600536811029941 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)
title Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)
title_full Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)
title_fullStr Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)
title_full_unstemmed Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)
title_short Diaqua­bis­(N,N′-diethyl­nicotinamide-κN (1))bis­(4-fluoro­benzoato-κO)copper(II)
title_sort diaqua­bis­(n,n′-diethyl­nicotinamide-κn (1))bis­(4-fluoro­benzoato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212262/
https://www.ncbi.nlm.nih.gov/pubmed/22090919
http://dx.doi.org/10.1107/S1600536811029941
work_keys_str_mv AT necefogluhacali diaquabisnndiethylnicotinamidekn1bis4fluorobenzoatokocopperii
AT ozbekfureyaelif diaquabisnndiethylnicotinamidekn1bis4fluorobenzoatokocopperii
AT ozturkvijdan diaquabisnndiethylnicotinamidekn1bis4fluorobenzoatokocopperii
AT adıguzelvedat diaquabisnndiethylnicotinamidekn1bis4fluorobenzoatokocopperii
AT hokelektuncer diaquabisnndiethylnicotinamidekn1bis4fluorobenzoatokocopperii