Cargando…

9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol

In the title compound, C(19)H(20)F(3)NOS, the dihedral angle between the mean planes of the two benzene rings attached to the thioxanthene ring is 41.8 (7)°; the latter has a slightly distorted boat conformation. The F atoms are disordered over three sets of sites [occupancy ratio = 0.564 (10):0.287...

Descripción completa

Detalles Bibliográficos
Autores principales: Jasinski, Jerry P., Golen, James A., Siddegowda, M. S., Yathirajan, H. S., Swamy, M. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212278/
https://www.ncbi.nlm.nih.gov/pubmed/22090935
http://dx.doi.org/10.1107/S1600536811025311
_version_ 1782215958844145664
author Jasinski, Jerry P.
Golen, James A.
Siddegowda, M. S.
Yathirajan, H. S.
Swamy, M. T.
author_facet Jasinski, Jerry P.
Golen, James A.
Siddegowda, M. S.
Yathirajan, H. S.
Swamy, M. T.
author_sort Jasinski, Jerry P.
collection PubMed
description In the title compound, C(19)H(20)F(3)NOS, the dihedral angle between the mean planes of the two benzene rings attached to the thioxanthene ring is 41.8 (7)°; the latter has a slightly distorted boat conformation. The F atoms are disordered over three sets of sites [occupancy ratio = 0.564 (10):0.287 (10):0.148 (5)] and the methyl groups are disordered over two sets of sites [occupancy ratio = 0.72 (4):0.28 (4)]. The crystal packing is stabilized by O—H⋯N and C—H⋯S hydrogen bonds and weak C—H⋯Cg inter­actions.
format Online
Article
Text
id pubmed-3212278
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32122782011-11-16 9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol Jasinski, Jerry P. Golen, James A. Siddegowda, M. S. Yathirajan, H. S. Swamy, M. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(20)F(3)NOS, the dihedral angle between the mean planes of the two benzene rings attached to the thioxanthene ring is 41.8 (7)°; the latter has a slightly distorted boat conformation. The F atoms are disordered over three sets of sites [occupancy ratio = 0.564 (10):0.287 (10):0.148 (5)] and the methyl groups are disordered over two sets of sites [occupancy ratio = 0.72 (4):0.28 (4)]. The crystal packing is stabilized by O—H⋯N and C—H⋯S hydrogen bonds and weak C—H⋯Cg inter­actions. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212278/ /pubmed/22090935 http://dx.doi.org/10.1107/S1600536811025311 Text en © Jasinski et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jasinski, Jerry P.
Golen, James A.
Siddegowda, M. S.
Yathirajan, H. S.
Swamy, M. T.
9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol
title 9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol
title_full 9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol
title_fullStr 9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol
title_full_unstemmed 9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol
title_short 9-[3-(Dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9H-thioxanthen-9-ol
title_sort 9-[3-(dimethyl­amino)­prop­yl]-2-trifluoro­meth­yl-9h-thioxanthen-9-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212278/
https://www.ncbi.nlm.nih.gov/pubmed/22090935
http://dx.doi.org/10.1107/S1600536811025311
work_keys_str_mv AT jasinskijerryp 93dimethylaminopropyl2trifluoromethyl9hthioxanthen9ol
AT golenjamesa 93dimethylaminopropyl2trifluoromethyl9hthioxanthen9ol
AT siddegowdams 93dimethylaminopropyl2trifluoromethyl9hthioxanthen9ol
AT yathirajanhs 93dimethylaminopropyl2trifluoromethyl9hthioxanthen9ol
AT swamymt 93dimethylaminopropyl2trifluoromethyl9hthioxanthen9ol