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9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol
In the title compound, C(19)H(20)F(3)NOS, the dihedral angle between the mean planes of the two benzene rings attached to the thioxanthene ring is 41.8 (7)°; the latter has a slightly distorted boat conformation. The F atoms are disordered over three sets of sites [occupancy ratio = 0.564 (10):0.287...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212278/ https://www.ncbi.nlm.nih.gov/pubmed/22090935 http://dx.doi.org/10.1107/S1600536811025311 |
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author | Jasinski, Jerry P. Golen, James A. Siddegowda, M. S. Yathirajan, H. S. Swamy, M. T. |
author_facet | Jasinski, Jerry P. Golen, James A. Siddegowda, M. S. Yathirajan, H. S. Swamy, M. T. |
author_sort | Jasinski, Jerry P. |
collection | PubMed |
description | In the title compound, C(19)H(20)F(3)NOS, the dihedral angle between the mean planes of the two benzene rings attached to the thioxanthene ring is 41.8 (7)°; the latter has a slightly distorted boat conformation. The F atoms are disordered over three sets of sites [occupancy ratio = 0.564 (10):0.287 (10):0.148 (5)] and the methyl groups are disordered over two sets of sites [occupancy ratio = 0.72 (4):0.28 (4)]. The crystal packing is stabilized by O—H⋯N and C—H⋯S hydrogen bonds and weak C—H⋯Cg interactions. |
format | Online Article Text |
id | pubmed-3212278 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32122782011-11-16 9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol Jasinski, Jerry P. Golen, James A. Siddegowda, M. S. Yathirajan, H. S. Swamy, M. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(20)F(3)NOS, the dihedral angle between the mean planes of the two benzene rings attached to the thioxanthene ring is 41.8 (7)°; the latter has a slightly distorted boat conformation. The F atoms are disordered over three sets of sites [occupancy ratio = 0.564 (10):0.287 (10):0.148 (5)] and the methyl groups are disordered over two sets of sites [occupancy ratio = 0.72 (4):0.28 (4)]. The crystal packing is stabilized by O—H⋯N and C—H⋯S hydrogen bonds and weak C—H⋯Cg interactions. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212278/ /pubmed/22090935 http://dx.doi.org/10.1107/S1600536811025311 Text en © Jasinski et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jasinski, Jerry P. Golen, James A. Siddegowda, M. S. Yathirajan, H. S. Swamy, M. T. 9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol |
title | 9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol |
title_full | 9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol |
title_fullStr | 9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol |
title_full_unstemmed | 9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol |
title_short | 9-[3-(Dimethylamino)propyl]-2-trifluoromethyl-9H-thioxanthen-9-ol |
title_sort | 9-[3-(dimethylamino)propyl]-2-trifluoromethyl-9h-thioxanthen-9-ol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212278/ https://www.ncbi.nlm.nih.gov/pubmed/22090935 http://dx.doi.org/10.1107/S1600536811025311 |
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