(E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate

The asymmetric unit of the title compound, C(10)H(12)N(2)O(3)·2H(2)O, contains two organic mol­ecules with similar conformations and four water mol­ecules. Each organic mol­ecule is close to planar (r.m.s. deviations = 0.035 and 0.108 Å) and adopts a trans conformation with respect to its C=N bond....

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Autores principales: Hu, Xian-Chao, Zhang, Jie, Yang, Da-Yong, Lv, Lu-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212279/
https://www.ncbi.nlm.nih.gov/pubmed/22090936
http://dx.doi.org/10.1107/S1600536811025104
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author Hu, Xian-Chao
Zhang, Jie
Yang, Da-Yong
Lv, Lu-Ping
author_facet Hu, Xian-Chao
Zhang, Jie
Yang, Da-Yong
Lv, Lu-Ping
author_sort Hu, Xian-Chao
collection PubMed
description The asymmetric unit of the title compound, C(10)H(12)N(2)O(3)·2H(2)O, contains two organic mol­ecules with similar conformations and four water mol­ecules. Each organic mol­ecule is close to planar (r.m.s. deviations = 0.035 and 0.108 Å) and adopts a trans conformation with respect to its C=N bond. In the crystal, the components are linked into a three-dimensional network by N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, some of which are bifurcated. An R (2) (2)(8) loop occurs between adjacent organic mol­ecules.
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spelling pubmed-32122792011-11-16 (E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate Hu, Xian-Chao Zhang, Jie Yang, Da-Yong Lv, Lu-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(12)N(2)O(3)·2H(2)O, contains two organic mol­ecules with similar conformations and four water mol­ecules. Each organic mol­ecule is close to planar (r.m.s. deviations = 0.035 and 0.108 Å) and adopts a trans conformation with respect to its C=N bond. In the crystal, the components are linked into a three-dimensional network by N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, some of which are bifurcated. An R (2) (2)(8) loop occurs between adjacent organic mol­ecules. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212279/ /pubmed/22090936 http://dx.doi.org/10.1107/S1600536811025104 Text en © Hu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Xian-Chao
Zhang, Jie
Yang, Da-Yong
Lv, Lu-Ping
(E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate
title (E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate
title_full (E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate
title_fullStr (E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate
title_full_unstemmed (E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate
title_short (E)-Ethyl N′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate
title_sort (e)-ethyl n′-(3-hy­droxy­benzyl­idene)hydrazinecarboxyl­ate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212279/
https://www.ncbi.nlm.nih.gov/pubmed/22090936
http://dx.doi.org/10.1107/S1600536811025104
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