2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate

The title salt, C(9)H(18)NO(+)·C(7)H(3)ClNO(4) (−), was obtained as an unexpected product of the reaction of 4-chloro-3-nitro­benzoyl isothio­cyanate with pyrrolidine. The six-membered ring of the 4-oxopiperidinium cation adopts a chair conformation. In the crystal structure, two cations and three a...

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Detalles Bibliográficos
Autores principales: Yamin, Bohari M., Zulkifli, Norsakina Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212310/
https://www.ncbi.nlm.nih.gov/pubmed/22090967
http://dx.doi.org/10.1107/S1600536811025074
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author Yamin, Bohari M.
Zulkifli, Norsakina Z.
author_facet Yamin, Bohari M.
Zulkifli, Norsakina Z.
author_sort Yamin, Bohari M.
collection PubMed
description The title salt, C(9)H(18)NO(+)·C(7)H(3)ClNO(4) (−), was obtained as an unexpected product of the reaction of 4-chloro-3-nitro­benzoyl isothio­cyanate with pyrrolidine. The six-membered ring of the 4-oxopiperidinium cation adopts a chair conformation. In the crystal structure, two cations and three anions are linked together by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and arranged diagonally along the ac face.
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spelling pubmed-32123102011-11-16 2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate Yamin, Bohari M. Zulkifli, Norsakina Z. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(9)H(18)NO(+)·C(7)H(3)ClNO(4) (−), was obtained as an unexpected product of the reaction of 4-chloro-3-nitro­benzoyl isothio­cyanate with pyrrolidine. The six-membered ring of the 4-oxopiperidinium cation adopts a chair conformation. In the crystal structure, two cations and three anions are linked together by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and arranged diagonally along the ac face. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212310/ /pubmed/22090967 http://dx.doi.org/10.1107/S1600536811025074 Text en © Yamin and Zulkifli 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamin, Bohari M.
Zulkifli, Norsakina Z.
2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate
title 2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate
title_full 2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate
title_fullStr 2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate
title_full_unstemmed 2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate
title_short 2,2,6,6-Tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate
title_sort 2,2,6,6-tetra­methyl-4-oxopiperidin-1-ium 4-chloro-3-nitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212310/
https://www.ncbi.nlm.nih.gov/pubmed/22090967
http://dx.doi.org/10.1107/S1600536811025074
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