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Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)

The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-mol­ecules, the bis­(4-pyrid­yl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide mol­ecul...

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Detalles Bibliográficos
Autor principal: Wang, Guang-Yin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212313/
https://www.ncbi.nlm.nih.gov/pubmed/22090970
http://dx.doi.org/10.1107/S1600536811025694
Descripción
Sumario:The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-mol­ecules, the bis­(4-pyrid­yl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide mol­ecule, the dihedral angle between the two pyridine rings is 86.8 (1)°, while the carboxyl groups of the substituted quinone lie essentially in the plane of the benzene ring [dihedral angle = 5.3 (1)°]. In the crystal, the components are linked via inter­molecular O—H⋯N hydrogen bonds into zigzag chains which extend along c and are inter­linked through C—H⋯π associations.