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Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1)
The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-molecules, the bis(4-pyridyl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenylenebis(oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide molecul...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212313/ https://www.ncbi.nlm.nih.gov/pubmed/22090970 http://dx.doi.org/10.1107/S1600536811025694 |
Sumario: | The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-molecules, the bis(4-pyridyl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenylenebis(oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide molecule, the dihedral angle between the two pyridine rings is 86.8 (1)°, while the carboxyl groups of the substituted quinone lie essentially in the plane of the benzene ring [dihedral angle = 5.3 (1)°]. In the crystal, the components are linked via intermolecular O—H⋯N hydrogen bonds into zigzag chains which extend along c and are interlinked through C—H⋯π associations. |
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