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Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)

The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-mol­ecules, the bis­(4-pyrid­yl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide mol­ecul...

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Autor principal: Wang, Guang-Yin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212313/
https://www.ncbi.nlm.nih.gov/pubmed/22090970
http://dx.doi.org/10.1107/S1600536811025694
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author Wang, Guang-Yin
author_facet Wang, Guang-Yin
author_sort Wang, Guang-Yin
collection PubMed
description The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-mol­ecules, the bis­(4-pyrid­yl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide mol­ecule, the dihedral angle between the two pyridine rings is 86.8 (1)°, while the carboxyl groups of the substituted quinone lie essentially in the plane of the benzene ring [dihedral angle = 5.3 (1)°]. In the crystal, the components are linked via inter­molecular O—H⋯N hydrogen bonds into zigzag chains which extend along c and are inter­linked through C—H⋯π associations.
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spelling pubmed-32123132011-11-16 Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1) Wang, Guang-Yin Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-mol­ecules, the bis­(4-pyrid­yl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide mol­ecule, the dihedral angle between the two pyridine rings is 86.8 (1)°, while the carboxyl groups of the substituted quinone lie essentially in the plane of the benzene ring [dihedral angle = 5.3 (1)°]. In the crystal, the components are linked via inter­molecular O—H⋯N hydrogen bonds into zigzag chains which extend along c and are inter­linked through C—H⋯π associations. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212313/ /pubmed/22090970 http://dx.doi.org/10.1107/S1600536811025694 Text en © Guang-Yin Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Guang-Yin
Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)
title Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)
title_full Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)
title_fullStr Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)
title_full_unstemmed Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)
title_short Bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)
title_sort bis(4-pyrid­yl) disulfide–2,2′-[(p-phenyl­enebis(­oxy)]diacetic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212313/
https://www.ncbi.nlm.nih.gov/pubmed/22090970
http://dx.doi.org/10.1107/S1600536811025694
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