Cargando…
Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1)
The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-molecules, the bis(4-pyridyl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenylenebis(oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide molecul...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212313/ https://www.ncbi.nlm.nih.gov/pubmed/22090970 http://dx.doi.org/10.1107/S1600536811025694 |
_version_ | 1782215966955929600 |
---|---|
author | Wang, Guang-Yin |
author_facet | Wang, Guang-Yin |
author_sort | Wang, Guang-Yin |
collection | PubMed |
description | The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-molecules, the bis(4-pyridyl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenylenebis(oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide molecule, the dihedral angle between the two pyridine rings is 86.8 (1)°, while the carboxyl groups of the substituted quinone lie essentially in the plane of the benzene ring [dihedral angle = 5.3 (1)°]. In the crystal, the components are linked via intermolecular O—H⋯N hydrogen bonds into zigzag chains which extend along c and are interlinked through C—H⋯π associations. |
format | Online Article Text |
id | pubmed-3212313 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32123132011-11-16 Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) Wang, Guang-Yin Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title 1:1 co-crystal, C(10)H(8)N(2)S(2)·C(10)H(10)O(6), comprises two half-molecules, the bis(4-pyridyl) disulfide having twofold rotational symmetry and the 2,2′-[(p-phenylenebis(oxy)]diacetic acid having crystallographic inversion symmetry. In the disulfide molecule, the dihedral angle between the two pyridine rings is 86.8 (1)°, while the carboxyl groups of the substituted quinone lie essentially in the plane of the benzene ring [dihedral angle = 5.3 (1)°]. In the crystal, the components are linked via intermolecular O—H⋯N hydrogen bonds into zigzag chains which extend along c and are interlinked through C—H⋯π associations. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212313/ /pubmed/22090970 http://dx.doi.org/10.1107/S1600536811025694 Text en © Guang-Yin Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Guang-Yin Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) |
title | Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) |
title_full | Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) |
title_fullStr | Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) |
title_full_unstemmed | Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) |
title_short | Bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) |
title_sort | bis(4-pyridyl) disulfide–2,2′-[(p-phenylenebis(oxy)]diacetic acid (1/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212313/ https://www.ncbi.nlm.nih.gov/pubmed/22090970 http://dx.doi.org/10.1107/S1600536811025694 |
work_keys_str_mv | AT wangguangyin bis4pyridyldisulfide22pphenylenebisoxydiaceticacid11 |