4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)

The asymmetric unit of the title structure, C(14)H(30)N(2)O(4) (2+)·2PF(6) (−), contains the anion and half of the cation, the latter being completed by a crystallographic twofold axis. The cation has a cage structure with the ammonium H atoms pointing into the cage. These H atoms are shielded from...

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Detalles Bibliográficos
Autores principales: Sen Gupta, Nalinava, Wragg, David S., Tilset, Mats, Omtvedt, Jon Petter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212317/
https://www.ncbi.nlm.nih.gov/pubmed/22090974
http://dx.doi.org/10.1107/S1600536811025992
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author Sen Gupta, Nalinava
Wragg, David S.
Tilset, Mats
Omtvedt, Jon Petter
author_facet Sen Gupta, Nalinava
Wragg, David S.
Tilset, Mats
Omtvedt, Jon Petter
author_sort Sen Gupta, Nalinava
collection PubMed
description The asymmetric unit of the title structure, C(14)H(30)N(2)O(4) (2+)·2PF(6) (−), contains the anion and half of the cation, the latter being completed by a crystallographic twofold axis. The cation has a cage structure with the ammonium H atoms pointing into the cage. These H atoms are shielded from inter­molecular inter­actions and form only intra­molecular contacts. There are short inter­molecular C—H⋯F inter­actions in the structure, but no conventional inter­molecular hydrogen bonds.
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spelling pubmed-32123172011-11-16 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate) Sen Gupta, Nalinava Wragg, David S. Tilset, Mats Omtvedt, Jon Petter Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title structure, C(14)H(30)N(2)O(4) (2+)·2PF(6) (−), contains the anion and half of the cation, the latter being completed by a crystallographic twofold axis. The cation has a cage structure with the ammonium H atoms pointing into the cage. These H atoms are shielded from inter­molecular inter­actions and form only intra­molecular contacts. There are short inter­molecular C—H⋯F inter­actions in the structure, but no conventional inter­molecular hydrogen bonds. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212317/ /pubmed/22090974 http://dx.doi.org/10.1107/S1600536811025992 Text en © Sen Gupta et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sen Gupta, Nalinava
Wragg, David S.
Tilset, Mats
Omtvedt, Jon Petter
4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)
title 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)
title_full 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)
title_fullStr 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)
title_full_unstemmed 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)
title_short 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)
title_sort 4,7,13,18-tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane bis­(hexa­fluorido­phosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212317/
https://www.ncbi.nlm.nih.gov/pubmed/22090974
http://dx.doi.org/10.1107/S1600536811025992
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