Methyl 6-azido-6-de­oxy-α-d-galactoside

The structure of the title compound, C(7)H(13)N(3)O(5), was solved using data from a multiple fragment crystal. The galactoside ring adopts a (4) C (1) chair conformation. In the crystal, the molecules are linked by strong O—H⋯O hydrogen bonds, which build linkages around the screw axis of the cell...

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Autores principales: Cheng, Janice M. H., Gulab, Shivali A., Timmer, Mattie S. M., Stocker, Bridget L., Gainsford, Graeme J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212328/
https://www.ncbi.nlm.nih.gov/pubmed/22090985
http://dx.doi.org/10.1107/S1600536811025323
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author Cheng, Janice M. H.
Gulab, Shivali A.
Timmer, Mattie S. M.
Stocker, Bridget L.
Gainsford, Graeme J.
author_facet Cheng, Janice M. H.
Gulab, Shivali A.
Timmer, Mattie S. M.
Stocker, Bridget L.
Gainsford, Graeme J.
author_sort Cheng, Janice M. H.
collection PubMed
description The structure of the title compound, C(7)H(13)N(3)O(5), was solved using data from a multiple fragment crystal. The galactoside ring adopts a (4) C (1) chair conformation. In the crystal, the molecules are linked by strong O—H⋯O hydrogen bonds, which build linkages around the screw axis of the cell in a similar way to the iodo analogue. These C-5 and C-6 packing motifs expand to R (2) (2)(10), C (2) (2)(7) and C (2) (2) (2)(8) motifs, as found in closely related compounds.
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spelling pubmed-32123282011-11-16 Methyl 6-azido-6-de­oxy-α-d-galactoside Cheng, Janice M. H. Gulab, Shivali A. Timmer, Mattie S. M. Stocker, Bridget L. Gainsford, Graeme J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound, C(7)H(13)N(3)O(5), was solved using data from a multiple fragment crystal. The galactoside ring adopts a (4) C (1) chair conformation. In the crystal, the molecules are linked by strong O—H⋯O hydrogen bonds, which build linkages around the screw axis of the cell in a similar way to the iodo analogue. These C-5 and C-6 packing motifs expand to R (2) (2)(10), C (2) (2)(7) and C (2) (2) (2)(8) motifs, as found in closely related compounds. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212328/ /pubmed/22090985 http://dx.doi.org/10.1107/S1600536811025323 Text en © Cheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Janice M. H.
Gulab, Shivali A.
Timmer, Mattie S. M.
Stocker, Bridget L.
Gainsford, Graeme J.
Methyl 6-azido-6-de­oxy-α-d-galactoside
title Methyl 6-azido-6-de­oxy-α-d-galactoside
title_full Methyl 6-azido-6-de­oxy-α-d-galactoside
title_fullStr Methyl 6-azido-6-de­oxy-α-d-galactoside
title_full_unstemmed Methyl 6-azido-6-de­oxy-α-d-galactoside
title_short Methyl 6-azido-6-de­oxy-α-d-galactoside
title_sort methyl 6-azido-6-de­oxy-α-d-galactoside
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212328/
https://www.ncbi.nlm.nih.gov/pubmed/22090985
http://dx.doi.org/10.1107/S1600536811025323
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AT gulabshivalia methyl6azido6deoxyadgalactoside
AT timmermattiesm methyl6azido6deoxyadgalactoside
AT stockerbridgetl methyl6azido6deoxyadgalactoside
AT gainsfordgraemej methyl6azido6deoxyadgalactoside

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