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1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine

The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two mol­ecules (A and B) in the asymmetric unit. Both aromatic rings of both mol­ecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for mol­ecule A and 0.789 (3):0.211 (3) and 0.78...

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Detalles Bibliográficos
Autores principales: Samshuddin, S., Butcher, Ray J., Akkurt, Mehmet, Narayana, B., Yathirajan, H. S., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212338/
https://www.ncbi.nlm.nih.gov/pubmed/22090995
http://dx.doi.org/10.1107/S1600536811026547
Descripción
Sumario:The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two mol­ecules (A and B) in the asymmetric unit. Both aromatic rings of both mol­ecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for mol­ecule A and 0.789 (3):0.211 (3) and 0.789 (3):0.211 (3) for mol­ecule B]. The dihedral angles between the planes of the major and minor components of the disordered aromatic rings are 72.0 (4) and 71.2 (4)° for mol­ecule A, and 70.2 (4) and 71.5 (2)° for mol­ecule B. In the crystal, both mol­ecules form inversion dimers with R (2) (2)(6) ring motifs via pairs of inter­molecular O—H⋯N hydrogen bonds. The dimers are linked, forming zigzag C(7) chains along the c axis. Weak C—H⋯π inter­actions help to consolidate the packing.