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1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine
The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two molecules (A and B) in the asymmetric unit. Both aromatic rings of both molecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for molecule A and 0.789 (3):0.211 (3) and 0.78...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212338/ https://www.ncbi.nlm.nih.gov/pubmed/22090995 http://dx.doi.org/10.1107/S1600536811026547 |
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author | Samshuddin, S. Butcher, Ray J. Akkurt, Mehmet Narayana, B. Yathirajan, H. S. Sarojini, B. K. |
author_facet | Samshuddin, S. Butcher, Ray J. Akkurt, Mehmet Narayana, B. Yathirajan, H. S. Sarojini, B. K. |
author_sort | Samshuddin, S. |
collection | PubMed |
description | The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two molecules (A and B) in the asymmetric unit. Both aromatic rings of both molecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for molecule A and 0.789 (3):0.211 (3) and 0.789 (3):0.211 (3) for molecule B]. The dihedral angles between the planes of the major and minor components of the disordered aromatic rings are 72.0 (4) and 71.2 (4)° for molecule A, and 70.2 (4) and 71.5 (2)° for molecule B. In the crystal, both molecules form inversion dimers with R (2) (2)(6) ring motifs via pairs of intermolecular O—H⋯N hydrogen bonds. The dimers are linked, forming zigzag C(7) chains along the c axis. Weak C—H⋯π interactions help to consolidate the packing. |
format | Online Article Text |
id | pubmed-3212338 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32123382011-11-16 1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine Samshuddin, S. Butcher, Ray J. Akkurt, Mehmet Narayana, B. Yathirajan, H. S. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two molecules (A and B) in the asymmetric unit. Both aromatic rings of both molecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for molecule A and 0.789 (3):0.211 (3) and 0.789 (3):0.211 (3) for molecule B]. The dihedral angles between the planes of the major and minor components of the disordered aromatic rings are 72.0 (4) and 71.2 (4)° for molecule A, and 70.2 (4) and 71.5 (2)° for molecule B. In the crystal, both molecules form inversion dimers with R (2) (2)(6) ring motifs via pairs of intermolecular O—H⋯N hydrogen bonds. The dimers are linked, forming zigzag C(7) chains along the c axis. Weak C—H⋯π interactions help to consolidate the packing. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212338/ /pubmed/22090995 http://dx.doi.org/10.1107/S1600536811026547 Text en © Samshuddin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Samshuddin, S. Butcher, Ray J. Akkurt, Mehmet Narayana, B. Yathirajan, H. S. Sarojini, B. K. 1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine |
title | 1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine |
title_full | 1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine |
title_fullStr | 1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine |
title_full_unstemmed | 1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine |
title_short | 1,3-Bis(4-fluorophenyl)-N,N′-(propane-1,3-diylidene)dihydroxylamine |
title_sort | 1,3-bis(4-fluorophenyl)-n,n′-(propane-1,3-diylidene)dihydroxylamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212338/ https://www.ncbi.nlm.nih.gov/pubmed/22090995 http://dx.doi.org/10.1107/S1600536811026547 |
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