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1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine

The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two mol­ecules (A and B) in the asymmetric unit. Both aromatic rings of both mol­ecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for mol­ecule A and 0.789 (3):0.211 (3) and 0.78...

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Autores principales: Samshuddin, S., Butcher, Ray J., Akkurt, Mehmet, Narayana, B., Yathirajan, H. S., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212338/
https://www.ncbi.nlm.nih.gov/pubmed/22090995
http://dx.doi.org/10.1107/S1600536811026547
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author Samshuddin, S.
Butcher, Ray J.
Akkurt, Mehmet
Narayana, B.
Yathirajan, H. S.
Sarojini, B. K.
author_facet Samshuddin, S.
Butcher, Ray J.
Akkurt, Mehmet
Narayana, B.
Yathirajan, H. S.
Sarojini, B. K.
author_sort Samshuddin, S.
collection PubMed
description The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two mol­ecules (A and B) in the asymmetric unit. Both aromatic rings of both mol­ecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for mol­ecule A and 0.789 (3):0.211 (3) and 0.789 (3):0.211 (3) for mol­ecule B]. The dihedral angles between the planes of the major and minor components of the disordered aromatic rings are 72.0 (4) and 71.2 (4)° for mol­ecule A, and 70.2 (4) and 71.5 (2)° for mol­ecule B. In the crystal, both mol­ecules form inversion dimers with R (2) (2)(6) ring motifs via pairs of inter­molecular O—H⋯N hydrogen bonds. The dimers are linked, forming zigzag C(7) chains along the c axis. Weak C—H⋯π inter­actions help to consolidate the packing.
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spelling pubmed-32123382011-11-16 1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine Samshuddin, S. Butcher, Ray J. Akkurt, Mehmet Narayana, B. Yathirajan, H. S. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)F(2)N(2)O(2), crystallizes with two mol­ecules (A and B) in the asymmetric unit. Both aromatic rings of both mol­ecules are disordered over two orientations [occupancy ratios of 0.768 (3):0.232 (3) and 0.770 (3):0.230 (3) for mol­ecule A and 0.789 (3):0.211 (3) and 0.789 (3):0.211 (3) for mol­ecule B]. The dihedral angles between the planes of the major and minor components of the disordered aromatic rings are 72.0 (4) and 71.2 (4)° for mol­ecule A, and 70.2 (4) and 71.5 (2)° for mol­ecule B. In the crystal, both mol­ecules form inversion dimers with R (2) (2)(6) ring motifs via pairs of inter­molecular O—H⋯N hydrogen bonds. The dimers are linked, forming zigzag C(7) chains along the c axis. Weak C—H⋯π inter­actions help to consolidate the packing. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212338/ /pubmed/22090995 http://dx.doi.org/10.1107/S1600536811026547 Text en © Samshuddin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Samshuddin, S.
Butcher, Ray J.
Akkurt, Mehmet
Narayana, B.
Yathirajan, H. S.
Sarojini, B. K.
1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine
title 1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine
title_full 1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine
title_fullStr 1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine
title_full_unstemmed 1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine
title_short 1,3-Bis(4-fluoro­phen­yl)-N,N′-(propane-1,3-diyl­idene)dihydroxyl­amine
title_sort 1,3-bis(4-fluoro­phen­yl)-n,n′-(propane-1,3-diyl­idene)dihydroxyl­amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212338/
https://www.ncbi.nlm.nih.gov/pubmed/22090995
http://dx.doi.org/10.1107/S1600536811026547
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