(E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate

The asymmetric unit of the title compound, C(11)H(11)N(3)O(2)·0.25H(2)O, contains two independent organic mol­ecules and a water mol­ecule, which lies on a twofold rotation axis. The side chains of the two mol­ecules have slightly different orientations, the C=N—N—C torsion angle being −163.03 (15)°...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Tie-Ming, Yu, Wen-Bo, Hu, Xian-Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212339/
https://www.ncbi.nlm.nih.gov/pubmed/22090996
http://dx.doi.org/10.1107/S1600536811026249
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author Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The asymmetric unit of the title compound, C(11)H(11)N(3)O(2)·0.25H(2)O, contains two independent organic mol­ecules and a water mol­ecule, which lies on a twofold rotation axis. The side chains of the two mol­ecules have slightly different orientations, the C=N—N—C torsion angle being −163.03 (15)° in one and −177.52 (14)° in the other, with each adopting a trans configuration with respect to the C=N bond. In the crystal, mol­ecules are linked into chains extending along b by N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds and in addition, four inter­molecular C—H⋯π inter­actions are present.
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spelling pubmed-32123392011-11-16 (E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate Lv, Lu-Ping Yu, Tie-Ming Yu, Wen-Bo Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(11)N(3)O(2)·0.25H(2)O, contains two independent organic mol­ecules and a water mol­ecule, which lies on a twofold rotation axis. The side chains of the two mol­ecules have slightly different orientations, the C=N—N—C torsion angle being −163.03 (15)° in one and −177.52 (14)° in the other, with each adopting a trans configuration with respect to the C=N bond. In the crystal, mol­ecules are linked into chains extending along b by N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds and in addition, four inter­molecular C—H⋯π inter­actions are present. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212339/ /pubmed/22090996 http://dx.doi.org/10.1107/S1600536811026249 Text en © Lv et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Tie-Ming
Yu, Wen-Bo
Hu, Xian-Chao
(E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate
title (E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate
title_full (E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate
title_fullStr (E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate
title_full_unstemmed (E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate
title_short (E)-Methyl N′-[(1H-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate
title_sort (e)-methyl n′-[(1h-indol-3-yl)methyl­idene]hydrazinecarboxyl­ate 0.25-hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212339/
https://www.ncbi.nlm.nih.gov/pubmed/22090996
http://dx.doi.org/10.1107/S1600536811026249
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