Cargando…

4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate

The asymmetric unit of the title molecular salt, C(14)H(30)N(2)O(4) (2+)·SiF(6) (2−), contains half of both the anion and the cation, both ions being completed by a crystallographic twofold axis passing through the Si atom. The cation has a cage structure with the ammonium H atoms pointing into the...

Descripción completa

Detalles Bibliográficos
Autores principales: Sen Gupta, Nalinava, Wragg, David S., Tilset, Mats, Omtvedt, Jon Petter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212341/
https://www.ncbi.nlm.nih.gov/pubmed/22090998
http://dx.doi.org/10.1107/S1600536811026006
_version_ 1782215973712953344
author Sen Gupta, Nalinava
Wragg, David S.
Tilset, Mats
Omtvedt, Jon Petter
author_facet Sen Gupta, Nalinava
Wragg, David S.
Tilset, Mats
Omtvedt, Jon Petter
author_sort Sen Gupta, Nalinava
collection PubMed
description The asymmetric unit of the title molecular salt, C(14)H(30)N(2)O(4) (2+)·SiF(6) (2−), contains half of both the anion and the cation, both ions being completed by a crystallographic twofold axis passing through the Si atom. The cation has a cage structure with the ammonium H atoms pointing into the cage. These H atoms are shielded from inter­molecular inter­actions and form only intra­molecular contacts. There are short inter­molecular C—H⋯F inter­actions in the structure, but no conventional inter­molecular hydrogen bonds.
format Online
Article
Text
id pubmed-3212341
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32123412011-11-16 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate Sen Gupta, Nalinava Wragg, David S. Tilset, Mats Omtvedt, Jon Petter Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title molecular salt, C(14)H(30)N(2)O(4) (2+)·SiF(6) (2−), contains half of both the anion and the cation, both ions being completed by a crystallographic twofold axis passing through the Si atom. The cation has a cage structure with the ammonium H atoms pointing into the cage. These H atoms are shielded from inter­molecular inter­actions and form only intra­molecular contacts. There are short inter­molecular C—H⋯F inter­actions in the structure, but no conventional inter­molecular hydrogen bonds. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212341/ /pubmed/22090998 http://dx.doi.org/10.1107/S1600536811026006 Text en © Sen Gupta et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sen Gupta, Nalinava
Wragg, David S.
Tilset, Mats
Omtvedt, Jon Petter
4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate
title 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate
title_full 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate
title_fullStr 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate
title_full_unstemmed 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate
title_short 4,7,13,18-Tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate
title_sort 4,7,13,18-tetra­oxa-1,10-diazo­nia­bicyclo­[8.5.5]icosane hexa­fluorido­silicate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212341/
https://www.ncbi.nlm.nih.gov/pubmed/22090998
http://dx.doi.org/10.1107/S1600536811026006
work_keys_str_mv AT senguptanalinava 471318tetraoxa110diazoniabicyclo855icosanehexafluoridosilicate
AT wraggdavids 471318tetraoxa110diazoniabicyclo855icosanehexafluoridosilicate
AT tilsetmats 471318tetraoxa110diazoniabicyclo855icosanehexafluoridosilicate
AT omtvedtjonpetter 471318tetraoxa110diazoniabicyclo855icosanehexafluoridosilicate