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4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate
The asymmetric unit of the title molecular salt, C(14)H(30)N(2)O(4) (2+)·SiF(6) (2−), contains half of both the anion and the cation, both ions being completed by a crystallographic twofold axis passing through the Si atom. The cation has a cage structure with the ammonium H atoms pointing into the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212341/ https://www.ncbi.nlm.nih.gov/pubmed/22090998 http://dx.doi.org/10.1107/S1600536811026006 |
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author | Sen Gupta, Nalinava Wragg, David S. Tilset, Mats Omtvedt, Jon Petter |
author_facet | Sen Gupta, Nalinava Wragg, David S. Tilset, Mats Omtvedt, Jon Petter |
author_sort | Sen Gupta, Nalinava |
collection | PubMed |
description | The asymmetric unit of the title molecular salt, C(14)H(30)N(2)O(4) (2+)·SiF(6) (2−), contains half of both the anion and the cation, both ions being completed by a crystallographic twofold axis passing through the Si atom. The cation has a cage structure with the ammonium H atoms pointing into the cage. These H atoms are shielded from intermolecular interactions and form only intramolecular contacts. There are short intermolecular C—H⋯F interactions in the structure, but no conventional intermolecular hydrogen bonds. |
format | Online Article Text |
id | pubmed-3212341 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32123412011-11-16 4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate Sen Gupta, Nalinava Wragg, David S. Tilset, Mats Omtvedt, Jon Petter Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title molecular salt, C(14)H(30)N(2)O(4) (2+)·SiF(6) (2−), contains half of both the anion and the cation, both ions being completed by a crystallographic twofold axis passing through the Si atom. The cation has a cage structure with the ammonium H atoms pointing into the cage. These H atoms are shielded from intermolecular interactions and form only intramolecular contacts. There are short intermolecular C—H⋯F interactions in the structure, but no conventional intermolecular hydrogen bonds. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212341/ /pubmed/22090998 http://dx.doi.org/10.1107/S1600536811026006 Text en © Sen Gupta et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sen Gupta, Nalinava Wragg, David S. Tilset, Mats Omtvedt, Jon Petter 4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate |
title | 4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate |
title_full | 4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate |
title_fullStr | 4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate |
title_full_unstemmed | 4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate |
title_short | 4,7,13,18-Tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate |
title_sort | 4,7,13,18-tetraoxa-1,10-diazoniabicyclo[8.5.5]icosane hexafluoridosilicate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212341/ https://www.ncbi.nlm.nih.gov/pubmed/22090998 http://dx.doi.org/10.1107/S1600536811026006 |
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