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2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate
In the title compound, C(25)H(15)FN(4)·H(2)O, the fused ring system is essentially planar [maximum deviation of 0.0822 (14) Å]. The imidazole ring makes dihedral angles of 76.83 (7) and 32.22 (7)° with the phenyl group attached to nitrogen and the fluorobenzene group to carbon, respectively. The d...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212347/ https://www.ncbi.nlm.nih.gov/pubmed/22091004 http://dx.doi.org/10.1107/S1600536811026328 |
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| author | Rosepriya, S. Venkatesh Perumal, M. Thiruvalluvar, A. Jayabharathi, J. Butcher, R. J. Jasinski, J. P. Golen, J. A. |
| author_facet | Rosepriya, S. Venkatesh Perumal, M. Thiruvalluvar, A. Jayabharathi, J. Butcher, R. J. Jasinski, J. P. Golen, J. A. |
| author_sort | Rosepriya, S. |
| collection | PubMed |
| description | In the title compound, C(25)H(15)FN(4)·H(2)O, the fused ring system is essentially planar [maximum deviation of 0.0822 (14) Å]. The imidazole ring makes dihedral angles of 76.83 (7) and 32.22 (7)° with the phenyl group attached to nitrogen and the fluorobenzene group to carbon, respectively. The dihedral angle between the two phenyl rings is 72.13 (7)°. Intermolecular O—H⋯N, O—H⋯F, C—H⋯F, C—H⋯O and C—H⋯N hydrogen bonds are found in the crystal structure. |
| format | Online Article Text |
| id | pubmed-3212347 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32123472011-11-16 2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate Rosepriya, S. Venkatesh Perumal, M. Thiruvalluvar, A. Jayabharathi, J. Butcher, R. J. Jasinski, J. P. Golen, J. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(15)FN(4)·H(2)O, the fused ring system is essentially planar [maximum deviation of 0.0822 (14) Å]. The imidazole ring makes dihedral angles of 76.83 (7) and 32.22 (7)° with the phenyl group attached to nitrogen and the fluorobenzene group to carbon, respectively. The dihedral angle between the two phenyl rings is 72.13 (7)°. Intermolecular O—H⋯N, O—H⋯F, C—H⋯F, C—H⋯O and C—H⋯N hydrogen bonds are found in the crystal structure. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212347/ /pubmed/22091004 http://dx.doi.org/10.1107/S1600536811026328 Text en © Rosepriya et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Rosepriya, S. Venkatesh Perumal, M. Thiruvalluvar, A. Jayabharathi, J. Butcher, R. J. Jasinski, J. P. Golen, J. A. 2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate |
| title | 2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate |
| title_full | 2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate |
| title_fullStr | 2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate |
| title_full_unstemmed | 2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate |
| title_short | 2-(4-Fluorophenyl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate |
| title_sort | 2-(4-fluorophenyl)-1-phenyl-1h-imidazo[4,5-f][1,10]phenanthroline monohydrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212347/ https://www.ncbi.nlm.nih.gov/pubmed/22091004 http://dx.doi.org/10.1107/S1600536811026328 |
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