Ethyl 2-[(carbamothioyl­amino)­imino]­propano­ate

The title compound, C(6)H(11)N(3)O(2)S, consists of a roughly planar mol­ecule (r.m.s deviation from planarity = 0.077 Å for the non-H atoms) and has the S atom in an anti position to the imine N atom. This N atom is the acceptor of a strongly bent inter­nal N—H⋯N hydrogen bond donated by the amino...

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Detalles Bibliográficos
Autores principales: Corrêa, Charlane C., Graúdo, José Eugênio J.C., de Oliveira, Luiz Fernando C., de Almeida, Mauro V., Diniz, Renata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212349/
https://www.ncbi.nlm.nih.gov/pubmed/22091006
http://dx.doi.org/10.1107/S1600536811026237
Descripción
Sumario:The title compound, C(6)H(11)N(3)O(2)S, consists of a roughly planar mol­ecule (r.m.s deviation from planarity = 0.077 Å for the non-H atoms) and has the S atom in an anti position to the imine N atom. This N atom is the acceptor of a strongly bent inter­nal N—H⋯N hydrogen bond donated by the amino group. In the crystal, mol­ecules are arranged in undulating layers parallel to (010). The mol­ecules are linked via inter­molecular amino–carboxyl N—H⋯O hydrogen bonds, forming chains parallel to [001]. The chains are cross-linked by N(carbazone)—H⋯S and C—H⋯S inter­actions, forming infinite sheets.

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