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Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate
The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethylammonium cation and half of a 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate dianion. The anion lies on an inversion centre and the two carboxylate grou...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213430/ https://www.ncbi.nlm.nih.gov/pubmed/22091009 http://dx.doi.org/10.1107/S1600536811026511 |
Sumario: | The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethylammonium cation and half of a 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate dianion. The anion lies on an inversion centre and the two carboxylate groups are in trans positions based on the naphthaleneteracarboxylic diimide group. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations and anions, as well as by π–π interactions between the naphthaleneteracarboxylic diimide groups [centroid–centroid distance = 4.812 (3) Å]. |
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