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Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate

The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethyl­ammonium cation and half of a 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate dianion. The anion lies on an inversion centre and the two carboxyl­ate grou...

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Detalles Bibliográficos
Autores principales: Xu, Lan-Ping, Zhao, Wen-Na, Han, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213430/
https://www.ncbi.nlm.nih.gov/pubmed/22091009
http://dx.doi.org/10.1107/S1600536811026511
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author Xu, Lan-Ping
Zhao, Wen-Na
Han, Lei
author_facet Xu, Lan-Ping
Zhao, Wen-Na
Han, Lei
author_sort Xu, Lan-Ping
collection PubMed
description The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethyl­ammonium cation and half of a 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate dianion. The anion lies on an inversion centre and the two carboxyl­ate groups are in trans positions based on the naphthaleneteracarb­oxy­lic diimide group. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations and anions, as well as by π–π inter­actions between the naph­thaleneteracarb­oxy­lic diimide groups [centroid–centroid distance = 4.812 (3) Å].
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spelling pubmed-32134302011-11-16 Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate Xu, Lan-Ping Zhao, Wen-Na Han, Lei Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethyl­ammonium cation and half of a 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate dianion. The anion lies on an inversion centre and the two carboxyl­ate groups are in trans positions based on the naphthaleneteracarb­oxy­lic diimide group. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations and anions, as well as by π–π inter­actions between the naph­thaleneteracarb­oxy­lic diimide groups [centroid–centroid distance = 4.812 (3) Å]. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3213430/ /pubmed/22091009 http://dx.doi.org/10.1107/S1600536811026511 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Lan-Ping
Zhao, Wen-Na
Han, Lei
Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate
title Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate
title_full Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate
title_fullStr Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate
title_full_unstemmed Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate
title_short Bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate
title_sort bis(dimethyl­ammonium) 2,2′-(1,3,6,8-tetra­oxo-2,7-diaza­pyrene-2,7-di­yl)diacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213430/
https://www.ncbi.nlm.nih.gov/pubmed/22091009
http://dx.doi.org/10.1107/S1600536811026511
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