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Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate
The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethylammonium cation and half of a 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate dianion. The anion lies on an inversion centre and the two carboxylate grou...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213430/ https://www.ncbi.nlm.nih.gov/pubmed/22091009 http://dx.doi.org/10.1107/S1600536811026511 |
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author | Xu, Lan-Ping Zhao, Wen-Na Han, Lei |
author_facet | Xu, Lan-Ping Zhao, Wen-Na Han, Lei |
author_sort | Xu, Lan-Ping |
collection | PubMed |
description | The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethylammonium cation and half of a 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate dianion. The anion lies on an inversion centre and the two carboxylate groups are in trans positions based on the naphthaleneteracarboxylic diimide group. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations and anions, as well as by π–π interactions between the naphthaleneteracarboxylic diimide groups [centroid–centroid distance = 4.812 (3) Å]. |
format | Online Article Text |
id | pubmed-3213430 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32134302011-11-16 Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate Xu, Lan-Ping Zhao, Wen-Na Han, Lei Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of title compound, 2C(2)H(8)N(+)·C(18)H(8)N(2)O(8) (2−), comprises one crystallographically independent dimethylammonium cation and half of a 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate dianion. The anion lies on an inversion centre and the two carboxylate groups are in trans positions based on the naphthaleneteracarboxylic diimide group. The crystal packing is stabilized by N—H⋯O hydrogen bonds between cations and anions, as well as by π–π interactions between the naphthaleneteracarboxylic diimide groups [centroid–centroid distance = 4.812 (3) Å]. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3213430/ /pubmed/22091009 http://dx.doi.org/10.1107/S1600536811026511 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Xu, Lan-Ping Zhao, Wen-Na Han, Lei Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate |
title | Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate |
title_full | Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate |
title_fullStr | Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate |
title_full_unstemmed | Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate |
title_short | Bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate |
title_sort | bis(dimethylammonium) 2,2′-(1,3,6,8-tetraoxo-2,7-diazapyrene-2,7-diyl)diacetate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213430/ https://www.ncbi.nlm.nih.gov/pubmed/22091009 http://dx.doi.org/10.1107/S1600536811026511 |
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