Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate

The title compound, C(26)H(28)NO(3)P, crystallized with two independent mol­ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol­ecules are almost identical. The inter­planar angle between the anthracene and toluidine rings is similar in the two mol­ecules,...

Descripción completa

Detalles Bibliográficos
Autores principales: Kraicheva, Ivanka, Tsacheva, Ivelina, Vodenicharova, Elitsa, Tashev, Emil, Troev, Kolio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213438/
https://www.ncbi.nlm.nih.gov/pubmed/22091017
http://dx.doi.org/10.1107/S1600536811025943
_version_ 1782216123452751872
author Kraicheva, Ivanka
Tsacheva, Ivelina
Vodenicharova, Elitsa
Tashev, Emil
Troev, Kolio
author_facet Kraicheva, Ivanka
Tsacheva, Ivelina
Vodenicharova, Elitsa
Tashev, Emil
Troev, Kolio
author_sort Kraicheva, Ivanka
collection PubMed
description The title compound, C(26)H(28)NO(3)P, crystallized with two independent mol­ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol­ecules are almost identical. The inter­planar angle between the anthracene and toluidine rings is similar in the two mol­ecules, with values of 82.92 (5) and 80.70 (5)°. In the crystal, both molecules form inversion dimers linked by pairs of N—H⋯O hydrogen bonds. Three of the four ethyl groups are disordered over two sets of sites, the major components having occupancies of 0.748 (15), 0.77 (4) and 0.518 (19).
format Online
Article
Text
id pubmed-3213438
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32134382011-11-16 Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate Kraicheva, Ivanka Tsacheva, Ivelina Vodenicharova, Elitsa Tashev, Emil Troev, Kolio Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(28)NO(3)P, crystallized with two independent mol­ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol­ecules are almost identical. The inter­planar angle between the anthracene and toluidine rings is similar in the two mol­ecules, with values of 82.92 (5) and 80.70 (5)°. In the crystal, both molecules form inversion dimers linked by pairs of N—H⋯O hydrogen bonds. Three of the four ethyl groups are disordered over two sets of sites, the major components having occupancies of 0.748 (15), 0.77 (4) and 0.518 (19). International Union of Crystallography 2011-07-09 /pmc/articles/PMC3213438/ /pubmed/22091017 http://dx.doi.org/10.1107/S1600536811025943 Text en © Kraicheva et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kraicheva, Ivanka
Tsacheva, Ivelina
Vodenicharova, Elitsa
Tashev, Emil
Troev, Kolio
Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_full Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_fullStr Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_full_unstemmed Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_short Diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_sort diethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213438/
https://www.ncbi.nlm.nih.gov/pubmed/22091017
http://dx.doi.org/10.1107/S1600536811025943
work_keys_str_mv AT kraichevaivanka diethyl9anthryl4methylanilinomethylphosphonate
AT tsachevaivelina diethyl9anthryl4methylanilinomethylphosphonate
AT vodenicharovaelitsa diethyl9anthryl4methylanilinomethylphosphonate
AT tashevemil diethyl9anthryl4methylanilinomethylphosphonate
AT troevkolio diethyl9anthryl4methylanilinomethylphosphonate

Ejemplares similares