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1,5-Anhydro-2-deoxy-1,2-C-dichloromethylene-3,4,6-tri-O-(4-methoxybenzyl)-d-glycero-d-gulo-hexitol
The pyranosyl ring in the title compound, C(31)H(34)Cl(2)O(7), adopts a twist-boat conformation. The 4-methoxybenzyl groups are located in equatorial positions with the methoxy groups nearly coplanar with their respective rings [dihedral angles of 0.2 (3) and 9.4 (2)°]. The aromatic rings adopt o...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213466/ https://www.ncbi.nlm.nih.gov/pubmed/22091045 http://dx.doi.org/10.1107/S1600536811026870 |
| Sumario: | The pyranosyl ring in the title compound, C(31)H(34)Cl(2)O(7), adopts a twist-boat conformation. The 4-methoxybenzyl groups are located in equatorial positions with the methoxy groups nearly coplanar with their respective rings [dihedral angles of 0.2 (3) and 9.4 (2)°]. The aromatic rings adopt orientations enabling them to participate in C—H⋯π interactions with neighboring methoxy groups. The crystal structure is additionally stabilized by weak C—H⋯O interactions. |
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