1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol

The pyranosyl ring in the title compound, C(31)H(34)Cl(2)O(7), adopts a twist-boat conformation. The 4-meth­oxy­benzyl groups are located in equatorial positions with the meth­oxy groups nearly coplanar with their respective rings [dihedral angles of 0.2 (3) and 9.4 (2)°]. The aromatic rings adopt o...

Descripción completa

Detalles Bibliográficos
Autores principales: Kinfe, Henok H., Moshapo, Paseka T., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213466/
https://www.ncbi.nlm.nih.gov/pubmed/22091045
http://dx.doi.org/10.1107/S1600536811026870
_version_ 1782216129875279872
author Kinfe, Henok H.
Moshapo, Paseka T.
Muller, Alfred
author_facet Kinfe, Henok H.
Moshapo, Paseka T.
Muller, Alfred
author_sort Kinfe, Henok H.
collection PubMed
description The pyranosyl ring in the title compound, C(31)H(34)Cl(2)O(7), adopts a twist-boat conformation. The 4-meth­oxy­benzyl groups are located in equatorial positions with the meth­oxy groups nearly coplanar with their respective rings [dihedral angles of 0.2 (3) and 9.4 (2)°]. The aromatic rings adopt orientations enabling them to participate in C—H⋯π inter­actions with neighboring meth­oxy groups. The crystal structure is additionally stabilized by weak C—H⋯O inter­actions.
format Online
Article
Text
id pubmed-3213466
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32134662011-11-16 1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol Kinfe, Henok H. Moshapo, Paseka T. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers The pyranosyl ring in the title compound, C(31)H(34)Cl(2)O(7), adopts a twist-boat conformation. The 4-meth­oxy­benzyl groups are located in equatorial positions with the meth­oxy groups nearly coplanar with their respective rings [dihedral angles of 0.2 (3) and 9.4 (2)°]. The aromatic rings adopt orientations enabling them to participate in C—H⋯π inter­actions with neighboring meth­oxy groups. The crystal structure is additionally stabilized by weak C—H⋯O inter­actions. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3213466/ /pubmed/22091045 http://dx.doi.org/10.1107/S1600536811026870 Text en © Kinfe et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kinfe, Henok H.
Moshapo, Paseka T.
Muller, Alfred
1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol
title 1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol
title_full 1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol
title_fullStr 1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol
title_full_unstemmed 1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol
title_short 1,5-Anhydro-2-de­oxy-1,2-C-dichloro­methyl­ene-3,4,6-tri-O-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol
title_sort 1,5-anhydro-2-de­oxy-1,2-c-dichloro­methyl­ene-3,4,6-tri-o-(4-meth­oxy­benz­yl)-d-glycero-d-gulo-hexitol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213466/
https://www.ncbi.nlm.nih.gov/pubmed/22091045
http://dx.doi.org/10.1107/S1600536811026870
work_keys_str_mv AT kinfehenokh 15anhydro2deoxy12cdichloromethylene346trio4methoxybenzyldglycerodgulohexitol
AT moshapopasekat 15anhydro2deoxy12cdichloromethylene346trio4methoxybenzyldglycerodgulohexitol
AT mulleralfred 15anhydro2deoxy12cdichloromethylene346trio4methoxybenzyldglycerodgulohexitol

Ejemplares similares