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2-Chloro-N-(3,4-dimethylphenyl)benzamide
In the title compound, C(15)H(14)ClNO, the conformation of the N—H bond is anti to the meta-methyl group in the aniline ring, while that of the C=O bond is anti to the ortho-chloro group in the benzoyl ring. The mean planes through the two benzene rings make a dihedral angle of 80.8 (2)°. In the cry...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213471/ https://www.ncbi.nlm.nih.gov/pubmed/22091050 http://dx.doi.org/10.1107/S1600536811027267 |
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author | Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme |
author_facet | Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme |
author_sort | Rodrigues, Vinola Z. |
collection | PubMed |
description | In the title compound, C(15)H(14)ClNO, the conformation of the N—H bond is anti to the meta-methyl group in the aniline ring, while that of the C=O bond is anti to the ortho-chloro group in the benzoyl ring. The mean planes through the two benzene rings make a dihedral angle of 80.8 (2)°. In the crystal, molecules are linked by intermolecular N—H⋯O hydrogen bonds, forming column-like chains along the b axis. |
format | Online Article Text |
id | pubmed-3213471 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32134712011-11-16 2-Chloro-N-(3,4-dimethylphenyl)benzamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(14)ClNO, the conformation of the N—H bond is anti to the meta-methyl group in the aniline ring, while that of the C=O bond is anti to the ortho-chloro group in the benzoyl ring. The mean planes through the two benzene rings make a dihedral angle of 80.8 (2)°. In the crystal, molecules are linked by intermolecular N—H⋯O hydrogen bonds, forming column-like chains along the b axis. International Union of Crystallography 2011-07-13 /pmc/articles/PMC3213471/ /pubmed/22091050 http://dx.doi.org/10.1107/S1600536811027267 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme 2-Chloro-N-(3,4-dimethylphenyl)benzamide |
title | 2-Chloro-N-(3,4-dimethylphenyl)benzamide |
title_full | 2-Chloro-N-(3,4-dimethylphenyl)benzamide |
title_fullStr | 2-Chloro-N-(3,4-dimethylphenyl)benzamide |
title_full_unstemmed | 2-Chloro-N-(3,4-dimethylphenyl)benzamide |
title_short | 2-Chloro-N-(3,4-dimethylphenyl)benzamide |
title_sort | 2-chloro-n-(3,4-dimethylphenyl)benzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213471/ https://www.ncbi.nlm.nih.gov/pubmed/22091050 http://dx.doi.org/10.1107/S1600536811027267 |
work_keys_str_mv | AT rodriguesvinolaz 2chloron34dimethylphenylbenzamide AT forosabine 2chloron34dimethylphenylbenzamide AT gowdabthimme 2chloron34dimethylphenylbenzamide |