N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine

In the title compound, C(28)H(27)NP(2), the N atom adopts an almost planar geometry with the two P atoms and the C atom attached to it, with a distance of 0.066 (2) Å between the N atom and the C/P/P plane. The distorted trigonal–pyramidal geometry of the N atom is further illustrated by bond angles...

Descripción completa

Detalles Bibliográficos
Autores principales: Engelbrecht, Ilana, Visser, Hendrik G., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213490/
https://www.ncbi.nlm.nih.gov/pubmed/22091069
http://dx.doi.org/10.1107/S1600536811027656
_version_ 1782216135339409408
author Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_facet Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
author_sort Engelbrecht, Ilana
collection PubMed
description In the title compound, C(28)H(27)NP(2), the N atom adopts an almost planar geometry with the two P atoms and the C atom attached to it, with a distance of 0.066 (2) Å between the N atom and the C/P/P plane. The distorted trigonal–pyramidal geometry of the N atom is further illustrated by bond angles ranging between 115.22 (11) and 123.53 (8)°. Bond angles varying from 99.99 (9) to 108.07 (9) ° are indicative of the distorted pyramidal environment around the P atoms. An intra­molecular C—H⋯P hydrogen bond occurs. In the crystal, inter­molecular C—H⋯π inter­actions link the mol­ecules into a supra­molecular network.
format Online
Article
Text
id pubmed-3213490
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32134902011-11-16 N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine Engelbrecht, Ilana Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(27)NP(2), the N atom adopts an almost planar geometry with the two P atoms and the C atom attached to it, with a distance of 0.066 (2) Å between the N atom and the C/P/P plane. The distorted trigonal–pyramidal geometry of the N atom is further illustrated by bond angles ranging between 115.22 (11) and 123.53 (8)°. Bond angles varying from 99.99 (9) to 108.07 (9) ° are indicative of the distorted pyramidal environment around the P atoms. An intra­molecular C—H⋯P hydrogen bond occurs. In the crystal, inter­molecular C—H⋯π inter­actions link the mol­ecules into a supra­molecular network. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213490/ /pubmed/22091069 http://dx.doi.org/10.1107/S1600536811027656 Text en © Engelbrecht et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Engelbrecht, Ilana
Visser, Hendrik G.
Roodt, Andreas
N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine
title N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine
title_full N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine
title_fullStr N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine
title_full_unstemmed N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine
title_short N,N-Bis(diphenyl­phosphan­yl)cyclo­butanamine
title_sort n,n-bis(diphenyl­phosphan­yl)cyclo­butanamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213490/
https://www.ncbi.nlm.nih.gov/pubmed/22091069
http://dx.doi.org/10.1107/S1600536811027656
work_keys_str_mv AT engelbrechtilana nnbisdiphenylphosphanylcyclobutanamine
AT visserhendrikg nnbisdiphenylphosphanylcyclobutanamine
AT roodtandreas nnbisdiphenylphosphanylcyclobutanamine

Ejemplares similares