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rac-Dimethyl [(9-anthryl)(4-methylanilino)methyl]phosphonate
The title compound, C(24)H(24)NO(3)P, crystallizes as a racemate with two molecules in the asymmetric unit. The structural features (bond lengths and angles) of the two molecules are almost identical. The dihedral angle between the anthracene and toluidine rings is similar in the two molecules, w...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213493/ https://www.ncbi.nlm.nih.gov/pubmed/22091072 http://dx.doi.org/10.1107/S1600536811027711 |
Sumario: | The title compound, C(24)H(24)NO(3)P, crystallizes as a racemate with two molecules in the asymmetric unit. The structural features (bond lengths and angles) of the two molecules are almost identical. The dihedral angle between the anthracene and toluidine rings is similar in the two molecules, with values of 48.36 (9) and 51.15 (9)°. The methyl groups of one of the methoxy groups in one molecule is disordered over two sets of sites, the major component having a site occupancy of 0.636 (3). In the crystal, both molecules are linked into inversion dimers by pairs of N—H⋯O hydrogen bonds. |
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