rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate

The title compound, C(24)H(24)NO(3)P, crystallizes as a racemate with two mol­ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol­ecules are almost identical. The dihedral angle between the anthracene and toluidine rings is similar in the two mol­ecules, w...

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Autores principales: Kraicheva, Ivanka, Tsacheva, Ivelina, Vodenicharova, Elitsa, Tashev, Emil, Troev, Kolio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213493/
https://www.ncbi.nlm.nih.gov/pubmed/22091072
http://dx.doi.org/10.1107/S1600536811027711
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author Kraicheva, Ivanka
Tsacheva, Ivelina
Vodenicharova, Elitsa
Tashev, Emil
Troev, Kolio
author_facet Kraicheva, Ivanka
Tsacheva, Ivelina
Vodenicharova, Elitsa
Tashev, Emil
Troev, Kolio
author_sort Kraicheva, Ivanka
collection PubMed
description The title compound, C(24)H(24)NO(3)P, crystallizes as a racemate with two mol­ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol­ecules are almost identical. The dihedral angle between the anthracene and toluidine rings is similar in the two mol­ecules, with values of 48.36 (9) and 51.15 (9)°. The methyl groups of one of the meth­oxy groups in one mol­ecule is disordered over two sets of sites, the major component having a site occupancy of 0.636 (3). In the crystal, both molecules are linked into inversion dimers by pairs of N—H⋯O hydrogen bonds.
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spelling pubmed-32134932011-11-16 rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate Kraicheva, Ivanka Tsacheva, Ivelina Vodenicharova, Elitsa Tashev, Emil Troev, Kolio Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(24)NO(3)P, crystallizes as a racemate with two mol­ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol­ecules are almost identical. The dihedral angle between the anthracene and toluidine rings is similar in the two mol­ecules, with values of 48.36 (9) and 51.15 (9)°. The methyl groups of one of the meth­oxy groups in one mol­ecule is disordered over two sets of sites, the major component having a site occupancy of 0.636 (3). In the crystal, both molecules are linked into inversion dimers by pairs of N—H⋯O hydrogen bonds. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213493/ /pubmed/22091072 http://dx.doi.org/10.1107/S1600536811027711 Text en © Kraicheva et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kraicheva, Ivanka
Tsacheva, Ivelina
Vodenicharova, Elitsa
Tashev, Emil
Troev, Kolio
rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_full rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_fullStr rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_full_unstemmed rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_short rac-Dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
title_sort rac-dimethyl [(9-anthr­yl)(4-methyl­anilino)meth­yl]phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213493/
https://www.ncbi.nlm.nih.gov/pubmed/22091072
http://dx.doi.org/10.1107/S1600536811027711
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AT tashevemil racdimethyl9anthryl4methylanilinomethylphosphonate
AT troevkolio racdimethyl9anthryl4methylanilinomethylphosphonate

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