N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide

The P atom in the title compound, C(16)H(15)Cl(5)N(3)O(2)P, exhibits a tetra­hedral coordination geometry and the phosphoryl and carbonyl groups are anti with respect to one another. The dihedral angle between the benzene rings is 44.90 (15)°. One of the 2-chloro­benzyl­amido fragments is disordered...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Fadaei, Hassan, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213494/
https://www.ncbi.nlm.nih.gov/pubmed/22091073
http://dx.doi.org/10.1107/S1600536811027681
Descripción
Sumario:The P atom in the title compound, C(16)H(15)Cl(5)N(3)O(2)P, exhibits a tetra­hedral coordination geometry and the phosphoryl and carbonyl groups are anti with respect to one another. The dihedral angle between the benzene rings is 44.90 (15)°. One of the 2-chloro­benzyl­amido fragments is disordered over two sets of sites with occupancies of 0.8823 (17) and 0.1177 (17). In the crystal, adjacent mol­ecules are linked via N—H⋯O(P) and N—H⋯O(C) hydrogen bonds into an extended chain running parallel to the a axis.

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