N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide

The P atom in the title compound, C(16)H(15)Cl(5)N(3)O(2)P, exhibits a tetra­hedral coordination geometry and the phosphoryl and carbonyl groups are anti with respect to one another. The dihedral angle between the benzene rings is 44.90 (15)°. One of the 2-chloro­benzyl­amido fragments is disordered...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Fadaei, Hassan, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213494/
https://www.ncbi.nlm.nih.gov/pubmed/22091073
http://dx.doi.org/10.1107/S1600536811027681
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author Pourayoubi, Mehrdad
Fadaei, Hassan
Parvez, Masood
author_facet Pourayoubi, Mehrdad
Fadaei, Hassan
Parvez, Masood
author_sort Pourayoubi, Mehrdad
collection PubMed
description The P atom in the title compound, C(16)H(15)Cl(5)N(3)O(2)P, exhibits a tetra­hedral coordination geometry and the phosphoryl and carbonyl groups are anti with respect to one another. The dihedral angle between the benzene rings is 44.90 (15)°. One of the 2-chloro­benzyl­amido fragments is disordered over two sets of sites with occupancies of 0.8823 (17) and 0.1177 (17). In the crystal, adjacent mol­ecules are linked via N—H⋯O(P) and N—H⋯O(C) hydrogen bonds into an extended chain running parallel to the a axis.
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spelling pubmed-32134942011-11-16 N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide Pourayoubi, Mehrdad Fadaei, Hassan Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers The P atom in the title compound, C(16)H(15)Cl(5)N(3)O(2)P, exhibits a tetra­hedral coordination geometry and the phosphoryl and carbonyl groups are anti with respect to one another. The dihedral angle between the benzene rings is 44.90 (15)°. One of the 2-chloro­benzyl­amido fragments is disordered over two sets of sites with occupancies of 0.8823 (17) and 0.1177 (17). In the crystal, adjacent mol­ecules are linked via N—H⋯O(P) and N—H⋯O(C) hydrogen bonds into an extended chain running parallel to the a axis. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213494/ /pubmed/22091073 http://dx.doi.org/10.1107/S1600536811027681 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Fadaei, Hassan
Parvez, Masood
N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_full N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_fullStr N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_full_unstemmed N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_short N,N′-Bis(2-chloro­benz­yl)-N′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
title_sort n,n′-bis(2-chloro­benz­yl)-n′′-(2,2,2-trichloro­acet­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213494/
https://www.ncbi.nlm.nih.gov/pubmed/22091073
http://dx.doi.org/10.1107/S1600536811027681
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