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2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione

In the title compound, C(23)H(18)N(2)O(3), the inter­planar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinyl­idene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intra­molecular N—H⋯O hydrogen bond is observe...

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Detalles Bibliográficos
Autores principales: Bustos, Carlos, Barría, Daniela, Alvarez-Thon, Luis, Cárcamo, Juan-Guillermo, Garland, Maria Teresa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213496/
https://www.ncbi.nlm.nih.gov/pubmed/22091075
http://dx.doi.org/10.1107/S1600536811027590
Descripción
Sumario:In the title compound, C(23)H(18)N(2)O(3), the inter­planar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinyl­idene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intra­molecular N—H⋯O hydrogen bond is observed. The mol­ecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π inter­action [centroid–centroid distance of 3.5719 (10) Å]. These dimers are linked via weak C—H⋯O contacts, forming chains along the b axis.