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2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione
In the title compound, C(23)H(18)N(2)O(3), the interplanar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinylidene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intramolecular N—H⋯O hydrogen bond is observe...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213496/ https://www.ncbi.nlm.nih.gov/pubmed/22091075 http://dx.doi.org/10.1107/S1600536811027590 |
Sumario: | In the title compound, C(23)H(18)N(2)O(3), the interplanar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinylidene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intramolecular N—H⋯O hydrogen bond is observed. The molecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π interaction [centroid–centroid distance of 3.5719 (10) Å]. These dimers are linked via weak C—H⋯O contacts, forming chains along the b axis. |
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