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2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione

In the title compound, C(23)H(18)N(2)O(3), the inter­planar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinyl­idene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intra­molecular N—H⋯O hydrogen bond is observe...

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Detalles Bibliográficos
Autores principales: Bustos, Carlos, Barría, Daniela, Alvarez-Thon, Luis, Cárcamo, Juan-Guillermo, Garland, Maria Teresa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213496/
https://www.ncbi.nlm.nih.gov/pubmed/22091075
http://dx.doi.org/10.1107/S1600536811027590
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author Bustos, Carlos
Barría, Daniela
Alvarez-Thon, Luis
Cárcamo, Juan-Guillermo
Garland, Maria Teresa
author_facet Bustos, Carlos
Barría, Daniela
Alvarez-Thon, Luis
Cárcamo, Juan-Guillermo
Garland, Maria Teresa
author_sort Bustos, Carlos
collection PubMed
description In the title compound, C(23)H(18)N(2)O(3), the inter­planar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinyl­idene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intra­molecular N—H⋯O hydrogen bond is observed. The mol­ecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π inter­action [centroid–centroid distance of 3.5719 (10) Å]. These dimers are linked via weak C—H⋯O contacts, forming chains along the b axis.
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spelling pubmed-32134962011-11-16 2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione Bustos, Carlos Barría, Daniela Alvarez-Thon, Luis Cárcamo, Juan-Guillermo Garland, Maria Teresa Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(18)N(2)O(3), the inter­planar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinyl­idene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intra­molecular N—H⋯O hydrogen bond is observed. The mol­ecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π inter­action [centroid–centroid distance of 3.5719 (10) Å]. These dimers are linked via weak C—H⋯O contacts, forming chains along the b axis. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213496/ /pubmed/22091075 http://dx.doi.org/10.1107/S1600536811027590 Text en © Bustos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bustos, Carlos
Barría, Daniela
Alvarez-Thon, Luis
Cárcamo, Juan-Guillermo
Garland, Maria Teresa
2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title 2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_full 2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_fullStr 2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_full_unstemmed 2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_short 2-[2-(4-Acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_sort 2-[2-(4-acetyl­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213496/
https://www.ncbi.nlm.nih.gov/pubmed/22091075
http://dx.doi.org/10.1107/S1600536811027590
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