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2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione
In the title compound, C(23)H(18)N(2)O(3), the interplanar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinylidene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intramolecular N—H⋯O hydrogen bond is observe...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213496/ https://www.ncbi.nlm.nih.gov/pubmed/22091075 http://dx.doi.org/10.1107/S1600536811027590 |
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author | Bustos, Carlos Barría, Daniela Alvarez-Thon, Luis Cárcamo, Juan-Guillermo Garland, Maria Teresa |
author_facet | Bustos, Carlos Barría, Daniela Alvarez-Thon, Luis Cárcamo, Juan-Guillermo Garland, Maria Teresa |
author_sort | Bustos, Carlos |
collection | PubMed |
description | In the title compound, C(23)H(18)N(2)O(3), the interplanar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinylidene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intramolecular N—H⋯O hydrogen bond is observed. The molecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π interaction [centroid–centroid distance of 3.5719 (10) Å]. These dimers are linked via weak C—H⋯O contacts, forming chains along the b axis. |
format | Online Article Text |
id | pubmed-3213496 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32134962011-11-16 2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione Bustos, Carlos Barría, Daniela Alvarez-Thon, Luis Cárcamo, Juan-Guillermo Garland, Maria Teresa Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(18)N(2)O(3), the interplanar angle between the benzoyl units is 80.51 (6)° while the dihedral angles between the hydrazinylidene and benzoyl groups are 43.43 (6) and 54.16 (6)°. In the crystal, a strong resonance-assisted intramolecular N—H⋯O hydrogen bond is observed. The molecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π interaction [centroid–centroid distance of 3.5719 (10) Å]. These dimers are linked via weak C—H⋯O contacts, forming chains along the b axis. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213496/ /pubmed/22091075 http://dx.doi.org/10.1107/S1600536811027590 Text en © Bustos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bustos, Carlos Barría, Daniela Alvarez-Thon, Luis Cárcamo, Juan-Guillermo Garland, Maria Teresa 2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title | 2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_full | 2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_fullStr | 2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_full_unstemmed | 2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_short | 2-[2-(4-Acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_sort | 2-[2-(4-acetylphenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213496/ https://www.ncbi.nlm.nih.gov/pubmed/22091075 http://dx.doi.org/10.1107/S1600536811027590 |
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