2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide

The asymmetric unit of the title compound, C(11)H(15)NO(3)S, contains two independent mol­ecules in which the amide bonds show a trans conformation. The C—S—N—C torsion angles are −67.4 (2) and 63.8 (2)° in the two independent mol­ecules. In one of the mol­ecules, a methyl group is disordered over t...

Descripción completa

Detalles Bibliográficos
Autores principales: Shakuntala, K., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213502/
https://www.ncbi.nlm.nih.gov/pubmed/22091081
http://dx.doi.org/10.1107/S1600536811027838
_version_ 1782216138063609856
author Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_facet Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_sort Shakuntala, K.
collection PubMed
description The asymmetric unit of the title compound, C(11)H(15)NO(3)S, contains two independent mol­ecules in which the amide bonds show a trans conformation. The C—S—N—C torsion angles are −67.4 (2) and 63.8 (2)° in the two independent mol­ecules. In one of the mol­ecules, a methyl group is disordered over two sets of sites with a site-occupation factor of 0.661 (16) for the major occupany component. In the crystal, mol­ecules are packed into chains running along [101] through N—H⋯O(S) hydrogen bonds.
format Online
Article
Text
id pubmed-3213502
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32135022011-11-16 2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide Shakuntala, K. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(15)NO(3)S, contains two independent mol­ecules in which the amide bonds show a trans conformation. The C—S—N—C torsion angles are −67.4 (2) and 63.8 (2)° in the two independent mol­ecules. In one of the mol­ecules, a methyl group is disordered over two sets of sites with a site-occupation factor of 0.661 (16) for the major occupany component. In the crystal, mol­ecules are packed into chains running along [101] through N—H⋯O(S) hydrogen bonds. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213502/ /pubmed/22091081 http://dx.doi.org/10.1107/S1600536811027838 Text en © Shakuntala et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide
title 2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide
title_full 2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide
title_fullStr 2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide
title_full_unstemmed 2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide
title_short 2,2-Dimethyl-N-(2-methyl­phenyl­sulfon­yl)acetamide
title_sort 2,2-dimethyl-n-(2-methyl­phenyl­sulfon­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213502/
https://www.ncbi.nlm.nih.gov/pubmed/22091081
http://dx.doi.org/10.1107/S1600536811027838
work_keys_str_mv AT shakuntalak 22dimethyln2methylphenylsulfonylacetamide
AT forosabine 22dimethyln2methylphenylsulfonylacetamide
AT gowdabthimme 22dimethyln2methylphenylsulfonylacetamide

Ejemplares similares