1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate

The asymmetric unit of the title compound, C(17)H(13)N(4) (+)·BF(4) (−), contains one half of the benzimidazolium cation and one half of the tetra­fluoridoborate anion, with crystallographic mirror planes bis­ecting the mol­ecules. One F atom of the tetra­fluoridoborate is equally disordered about a...

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Detalles Bibliográficos
Autores principales: Grieco, Gabriele, Blacque, Olivier, Berke, Heinz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213512/
https://www.ncbi.nlm.nih.gov/pubmed/22091091
http://dx.doi.org/10.1107/S1600536811027942
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author Grieco, Gabriele
Blacque, Olivier
Berke, Heinz
author_facet Grieco, Gabriele
Blacque, Olivier
Berke, Heinz
author_sort Grieco, Gabriele
collection PubMed
description The asymmetric unit of the title compound, C(17)H(13)N(4) (+)·BF(4) (−), contains one half of the benzimidazolium cation and one half of the tetra­fluoridoborate anion, with crystallographic mirror planes bis­ecting the mol­ecules. One F atom of the tetra­fluoridoborate is equally disordered about a crystallographic mirror plane. In the crystal, C—H⋯F inter­actions link the cations and anions into layers parallel to (100). The crystal packing is further stabilized by F⋯π contacts involving the tetra­fluoridoborate anions and the five-membered rings [F⋯centroid = 2.811 (2) Å].
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spelling pubmed-32135122011-11-16 1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate Grieco, Gabriele Blacque, Olivier Berke, Heinz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(17)H(13)N(4) (+)·BF(4) (−), contains one half of the benzimidazolium cation and one half of the tetra­fluoridoborate anion, with crystallographic mirror planes bis­ecting the mol­ecules. One F atom of the tetra­fluoridoborate is equally disordered about a crystallographic mirror plane. In the crystal, C—H⋯F inter­actions link the cations and anions into layers parallel to (100). The crystal packing is further stabilized by F⋯π contacts involving the tetra­fluoridoborate anions and the five-membered rings [F⋯centroid = 2.811 (2) Å]. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213512/ /pubmed/22091091 http://dx.doi.org/10.1107/S1600536811027942 Text en © Grieco et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Grieco, Gabriele
Blacque, Olivier
Berke, Heinz
1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate
title 1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate
title_full 1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate
title_fullStr 1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate
title_full_unstemmed 1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate
title_short 1,3-Bis(pyridin-2-yl)-1H-benzimidazol-3-ium tetra­fluoridoborate
title_sort 1,3-bis(pyridin-2-yl)-1h-benzimidazol-3-ium tetra­fluoridoborate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213512/
https://www.ncbi.nlm.nih.gov/pubmed/22091091
http://dx.doi.org/10.1107/S1600536811027942
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