2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)

In the title mol­ecular salt, C(23)H(30)N(4) (2+)·2PF(6) (−), the central benzene ring of the cation makes dihedral angles of 89.80 (8) and 85.23 (7)° with the pendant imidazole rings. In the crystal, the cations and anions are linked by numerous C—H⋯F hydrogen bonds, thereby forming a three-dimensi...

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Autores principales: Haque, Rosenani A., Ghdhayeb, Mohammed Z., Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213513/
https://www.ncbi.nlm.nih.gov/pubmed/22091092
http://dx.doi.org/10.1107/S1600536811027541
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author Haque, Rosenani A.
Ghdhayeb, Mohammed Z.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Ghdhayeb, Mohammed Z.
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description In the title mol­ecular salt, C(23)H(30)N(4) (2+)·2PF(6) (−), the central benzene ring of the cation makes dihedral angles of 89.80 (8) and 85.23 (7)° with the pendant imidazole rings. In the crystal, the cations and anions are linked by numerous C—H⋯F hydrogen bonds, thereby forming a three-dimensional network.
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spelling pubmed-32135132011-11-16 2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate) Haque, Rosenani A. Ghdhayeb, Mohammed Z. Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt, C(23)H(30)N(4) (2+)·2PF(6) (−), the central benzene ring of the cation makes dihedral angles of 89.80 (8) and 85.23 (7)° with the pendant imidazole rings. In the crystal, the cations and anions are linked by numerous C—H⋯F hydrogen bonds, thereby forming a three-dimensional network. International Union of Crystallography 2011-07-16 /pmc/articles/PMC3213513/ /pubmed/22091092 http://dx.doi.org/10.1107/S1600536811027541 Text en © Haque et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Haque, Rosenani A.
Ghdhayeb, Mohammed Z.
Hemamalini, Madhukar
Fun, Hoong-Kun
2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)
title 2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)
title_full 2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)
title_fullStr 2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)
title_full_unstemmed 2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)
title_short 2,4-Bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)
title_sort 2,4-bis[(3-allyl­imidazolium-1-yl)meth­yl]mesitylene bis­(hexa­fluoridophosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213513/
https://www.ncbi.nlm.nih.gov/pubmed/22091092
http://dx.doi.org/10.1107/S1600536811027541
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