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6-Bromo-4-hydrazinylidene-1-methyl-3H-2λ(6),1-benzothiazine-2,2-dione
In the title molecule, C(9)H(10)BrN(3)O(2)S, the thiazine ring has an envelope conformation with the S atom at the flap. The geometry around the S atom is distorted tetrahedral. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds occur, generating R (2) (2)(6) ring motifs. N—...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213521/ https://www.ncbi.nlm.nih.gov/pubmed/22091100 http://dx.doi.org/10.1107/S1600536811027930 |
Sumario: | In the title molecule, C(9)H(10)BrN(3)O(2)S, the thiazine ring has an envelope conformation with the S atom at the flap. The geometry around the S atom is distorted tetrahedral. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds occur, generating R (2) (2)(6) ring motifs. N—H⋯O hydrogen bonds and C—H⋯O interactions connect the dimers, forming a three-dimentional network structure. |
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