6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione

In the title mol­ecule, C(9)H(10)BrN(3)O(2)S, the thia­zine ring has an envelope conformation with the S atom at the flap. The geometry around the S atom is distorted tetra­hedral. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds occur, generating R (2) (2)(6) ring motifs. N—...

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Detalles Bibliográficos
Autores principales: Shafiq, Muhammad, Khan, Islam Ullah, Zia-ur-Rehman, Muhammad, Arshad, Muhammad Nadeem, Asiri, Abdullah M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213521/
https://www.ncbi.nlm.nih.gov/pubmed/22091100
http://dx.doi.org/10.1107/S1600536811027930
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author Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
author_facet Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
author_sort Shafiq, Muhammad
collection PubMed
description In the title mol­ecule, C(9)H(10)BrN(3)O(2)S, the thia­zine ring has an envelope conformation with the S atom at the flap. The geometry around the S atom is distorted tetra­hedral. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds occur, generating R (2) (2)(6) ring motifs. N—H⋯O hydrogen bonds and C—H⋯O inter­actions connect the dimers, forming a three-dimentional network structure.
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spelling pubmed-32135212011-11-16 6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione Shafiq, Muhammad Khan, Islam Ullah Zia-ur-Rehman, Muhammad Arshad, Muhammad Nadeem Asiri, Abdullah M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(9)H(10)BrN(3)O(2)S, the thia­zine ring has an envelope conformation with the S atom at the flap. The geometry around the S atom is distorted tetra­hedral. In the crystal, inversion dimers linked by pairs of N—H⋯N hydrogen bonds occur, generating R (2) (2)(6) ring motifs. N—H⋯O hydrogen bonds and C—H⋯O inter­actions connect the dimers, forming a three-dimentional network structure. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213521/ /pubmed/22091100 http://dx.doi.org/10.1107/S1600536811027930 Text en © Shafiq et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione
title 6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione
title_full 6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione
title_fullStr 6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione
title_full_unstemmed 6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione
title_short 6-Bromo-4-hydrazinyl­idene-1-methyl-3H-2λ(6),1-benzothia­zine-2,2-dione
title_sort 6-bromo-4-hydrazinyl­idene-1-methyl-3h-2λ(6),1-benzothia­zine-2,2-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213521/
https://www.ncbi.nlm.nih.gov/pubmed/22091100
http://dx.doi.org/10.1107/S1600536811027930
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