6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine

In the title compound, C(11)H(11)ClN(4), the dihedral angle between the aromatic rings is 66.47 (8)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, generating C(5) chains propagating in [010]. Slipped aromatic π–π stacking between centrosymmetrically related pairs of pyrim­idine rin...

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Detalles Bibliográficos
Autores principales: Shi, Fuqiang, Zhu, Li-Hong, Zhang, Long, Li, Ya-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213532/
https://www.ncbi.nlm.nih.gov/pubmed/22091109
http://dx.doi.org/10.1107/S1600536811028303
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author Shi, Fuqiang
Zhu, Li-Hong
Zhang, Long
Li, Ya-Feng
author_facet Shi, Fuqiang
Zhu, Li-Hong
Zhang, Long
Li, Ya-Feng
author_sort Shi, Fuqiang
collection PubMed
description In the title compound, C(11)H(11)ClN(4), the dihedral angle between the aromatic rings is 66.47 (8)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, generating C(5) chains propagating in [010]. Slipped aromatic π–π stacking between centrosymmetrically related pairs of pyrim­idine rings also occurs [centroid–centroid separation = 3.7634 (12)Å and slippage = 1.715 Å].
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spelling pubmed-32135322011-11-16 6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine Shi, Fuqiang Zhu, Li-Hong Zhang, Long Li, Ya-Feng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(11)ClN(4), the dihedral angle between the aromatic rings is 66.47 (8)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, generating C(5) chains propagating in [010]. Slipped aromatic π–π stacking between centrosymmetrically related pairs of pyrim­idine rings also occurs [centroid–centroid separation = 3.7634 (12)Å and slippage = 1.715 Å]. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213532/ /pubmed/22091109 http://dx.doi.org/10.1107/S1600536811028303 Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shi, Fuqiang
Zhu, Li-Hong
Zhang, Long
Li, Ya-Feng
6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine
title 6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine
title_full 6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine
title_fullStr 6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine
title_full_unstemmed 6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine
title_short 6-Chloro-N (4)-methyl-N (4)-phenyl­pyrimidine-4,5-diamine
title_sort 6-chloro-n (4)-methyl-n (4)-phenyl­pyrimidine-4,5-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213532/
https://www.ncbi.nlm.nih.gov/pubmed/22091109
http://dx.doi.org/10.1107/S1600536811028303
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AT zhulihong 6chloron4methyln4phenylpyrimidine45diamine
AT zhanglong 6chloron4methyln4phenylpyrimidine45diamine
AT liyafeng 6chloron4methyln4phenylpyrimidine45diamine

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