6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione

In the title compound, C(17)H(16)BrN(3)O(2)S, the two fused rings are twisted by a dihedral angle of 6.61 (15)°. The thia­zine ring adopts a sofa conformation. The toluene ring is oriented at dihedral angles of 15.5 (2) and 20.6 (2)° with respect to the bromo­benzene and thia­zine rings, respectivel...

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Autores principales: Shafiq, Muhammad, Khan, Islam Ullah, Zia-ur-Rehman, Muhammad, Arshad, Muhammad Nadeem, Asiri, Abdullah M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213534/
https://www.ncbi.nlm.nih.gov/pubmed/22091111
http://dx.doi.org/10.1107/S1600536811028406
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author Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
author_facet Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
author_sort Shafiq, Muhammad
collection PubMed
description In the title compound, C(17)H(16)BrN(3)O(2)S, the two fused rings are twisted by a dihedral angle of 6.61 (15)°. The thia­zine ring adopts a sofa conformation. The toluene ring is oriented at dihedral angles of 15.5 (2) and 20.6 (2)° with respect to the bromo­benzene and thia­zine rings, respectively. The benzyl­idene system is approximately planar [r.m.s. deviation = 0.0388 Å]. In the cyrstal, weak inter­molecular C—H⋯O hydrogen bonds connects the mol­ecules into a chain along the b axis.
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spelling pubmed-32135342011-11-16 6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione Shafiq, Muhammad Khan, Islam Ullah Zia-ur-Rehman, Muhammad Arshad, Muhammad Nadeem Asiri, Abdullah M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(16)BrN(3)O(2)S, the two fused rings are twisted by a dihedral angle of 6.61 (15)°. The thia­zine ring adopts a sofa conformation. The toluene ring is oriented at dihedral angles of 15.5 (2) and 20.6 (2)° with respect to the bromo­benzene and thia­zine rings, respectively. The benzyl­idene system is approximately planar [r.m.s. deviation = 0.0388 Å]. In the cyrstal, weak inter­molecular C—H⋯O hydrogen bonds connects the mol­ecules into a chain along the b axis. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213534/ /pubmed/22091111 http://dx.doi.org/10.1107/S1600536811028406 Text en © Shafiq et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione
title 6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione
title_full 6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione
title_fullStr 6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione
title_full_unstemmed 6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione
title_short 6-Bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3H-2λ(6),1-benzothia­zine-2,2-dione
title_sort 6-bromo-1-methyl-4-[2-(4-methyl­benzyl­idene)hydrazinyl­idene]-3h-2λ(6),1-benzothia­zine-2,2-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213534/
https://www.ncbi.nlm.nih.gov/pubmed/22091111
http://dx.doi.org/10.1107/S1600536811028406
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