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N,N′-Bis(4-chlorophenylsulfonyl)suberamide
The asymmetric unit of the title compound, C(20)H(22)Cl(2)N(2)O(6)S(2), contains one half-molecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C=O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. Th...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213543/ https://www.ncbi.nlm.nih.gov/pubmed/22091120 http://dx.doi.org/10.1107/S1600536811028662 |
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author | Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme |
author_facet | Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme |
author_sort | Rodrigues, Vinola Z. |
collection | PubMed |
description | The asymmetric unit of the title compound, C(20)H(22)Cl(2)N(2)O(6)S(2), contains one half-molecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C=O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. The molecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of −80.6 (4)°. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—CH(2)—CH(2)—CH(2) segment is 79.5 (2)°. In the crystal, intermolecular N—H⋯O(C) and N—H⋯O(S) hydrogen bonds link the molecules into chains along the b axis. |
format | Online Article Text |
id | pubmed-3213543 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32135432011-11-16 N,N′-Bis(4-chlorophenylsulfonyl)suberamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(22)Cl(2)N(2)O(6)S(2), contains one half-molecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C=O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. The molecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of −80.6 (4)°. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—CH(2)—CH(2)—CH(2) segment is 79.5 (2)°. In the crystal, intermolecular N—H⋯O(C) and N—H⋯O(S) hydrogen bonds link the molecules into chains along the b axis. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213543/ /pubmed/22091120 http://dx.doi.org/10.1107/S1600536811028662 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme N,N′-Bis(4-chlorophenylsulfonyl)suberamide |
title |
N,N′-Bis(4-chlorophenylsulfonyl)suberamide |
title_full |
N,N′-Bis(4-chlorophenylsulfonyl)suberamide |
title_fullStr |
N,N′-Bis(4-chlorophenylsulfonyl)suberamide |
title_full_unstemmed |
N,N′-Bis(4-chlorophenylsulfonyl)suberamide |
title_short |
N,N′-Bis(4-chlorophenylsulfonyl)suberamide |
title_sort | n,n′-bis(4-chlorophenylsulfonyl)suberamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213543/ https://www.ncbi.nlm.nih.gov/pubmed/22091120 http://dx.doi.org/10.1107/S1600536811028662 |
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