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N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide

The asymmetric unit of the title compound, C(20)H(22)Cl(2)N(2)O(6)S(2), contains one half-mol­ecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C=O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. Th...

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Detalles Bibliográficos
Autores principales: Rodrigues, Vinola Z., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213543/
https://www.ncbi.nlm.nih.gov/pubmed/22091120
http://dx.doi.org/10.1107/S1600536811028662
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author Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_facet Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_sort Rodrigues, Vinola Z.
collection PubMed
description The asymmetric unit of the title compound, C(20)H(22)Cl(2)N(2)O(6)S(2), contains one half-mol­ecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C=O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of −80.6 (4)°. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—CH(2)—CH(2)—CH(2) segment is 79.5 (2)°. In the crystal, inter­molecular N—H⋯O(C) and N—H⋯O(S) hydrogen bonds link the mol­ecules into chains along the b axis.
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spelling pubmed-32135432011-11-16 N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(22)Cl(2)N(2)O(6)S(2), contains one half-mol­ecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C=O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C(O) torsion angle of −80.6 (4)°. The dihedral angle between the benzene ring and the SO(2)—NH—C(O)—CH(2)—CH(2)—CH(2) segment is 79.5 (2)°. In the crystal, inter­molecular N—H⋯O(C) and N—H⋯O(S) hydrogen bonds link the mol­ecules into chains along the b axis. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213543/ /pubmed/22091120 http://dx.doi.org/10.1107/S1600536811028662 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide
title N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide
title_full N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide
title_fullStr N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide
title_full_unstemmed N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide
title_short N,N′-Bis(4-chloro­phenyl­sulfon­yl)suberamide
title_sort n,n′-bis(4-chloro­phenyl­sulfon­yl)suberamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213543/
https://www.ncbi.nlm.nih.gov/pubmed/22091120
http://dx.doi.org/10.1107/S1600536811028662
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