2-Chloro­methyl-1-methyl-1,3-benzimidazole

The title compound, C(9)H(9)ClN(2), was prepared from the reaction of N-methyl­benzene-1,2-diamine and 2-chloro­acetic acid in boiling 6 M hydro­chloric acid. The benzimidazole unit is approximately planar, the largest deviation from the mean plane being 0.008 (1) Å. The Cl atom is displaced by 1.66...

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Detalles Bibliográficos
Autores principales: Han, Jie, Zhang, Jun, Yang, Qi, Zhao, Ming-gao, Fan, Guang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213546/
https://www.ncbi.nlm.nih.gov/pubmed/22091123
http://dx.doi.org/10.1107/S1600536811028376
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author Han, Jie
Zhang, Jun
Yang, Qi
Zhao, Ming-gao
Fan, Guang
author_facet Han, Jie
Zhang, Jun
Yang, Qi
Zhao, Ming-gao
Fan, Guang
author_sort Han, Jie
collection PubMed
description The title compound, C(9)H(9)ClN(2), was prepared from the reaction of N-methyl­benzene-1,2-diamine and 2-chloro­acetic acid in boiling 6 M hydro­chloric acid. The benzimidazole unit is approximately planar, the largest deviation from the mean plane being 0.008 (1) Å. The Cl atom is displaced by 1.667 (2) Å from this plane. The methyl group is statistically disordered with equal occupancy.
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spelling pubmed-32135462011-11-16 2-Chloro­methyl-1-methyl-1,3-benzimidazole Han, Jie Zhang, Jun Yang, Qi Zhao, Ming-gao Fan, Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(9)ClN(2), was prepared from the reaction of N-methyl­benzene-1,2-diamine and 2-chloro­acetic acid in boiling 6 M hydro­chloric acid. The benzimidazole unit is approximately planar, the largest deviation from the mean plane being 0.008 (1) Å. The Cl atom is displaced by 1.667 (2) Å from this plane. The methyl group is statistically disordered with equal occupancy. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213546/ /pubmed/22091123 http://dx.doi.org/10.1107/S1600536811028376 Text en © Han et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Han, Jie
Zhang, Jun
Yang, Qi
Zhao, Ming-gao
Fan, Guang
2-Chloro­methyl-1-methyl-1,3-benzimidazole
title 2-Chloro­methyl-1-methyl-1,3-benzimidazole
title_full 2-Chloro­methyl-1-methyl-1,3-benzimidazole
title_fullStr 2-Chloro­methyl-1-methyl-1,3-benzimidazole
title_full_unstemmed 2-Chloro­methyl-1-methyl-1,3-benzimidazole
title_short 2-Chloro­methyl-1-methyl-1,3-benzimidazole
title_sort 2-chloro­methyl-1-methyl-1,3-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213546/
https://www.ncbi.nlm.nih.gov/pubmed/22091123
http://dx.doi.org/10.1107/S1600536811028376
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AT zhangjun 2chloromethyl1methyl13benzimidazole
AT yangqi 2chloromethyl1methyl13benzimidazole
AT zhaominggao 2chloromethyl1methyl13benzimidazole
AT fanguang 2chloromethyl1methyl13benzimidazole

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