Cargando…
Benzyl 3-[(E)-1-(pyrazin-2-yl)ethylidene]dithiocarbazate
The title compound, C(14)H(14)N(4)S(2), was obtained from a condensation reaction of benzyl dithiocarbazate and acetylpyrazine. The asymmetric unit contains two independent molecules, in each of which the pyrazine ring and dithiocarbazate unit are approximately co-planar, the r.m.s. deviations b...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213547/ https://www.ncbi.nlm.nih.gov/pubmed/22091124 http://dx.doi.org/10.1107/S1600536811028480 |
Sumario: | The title compound, C(14)H(14)N(4)S(2), was obtained from a condensation reaction of benzyl dithiocarbazate and acetylpyrazine. The asymmetric unit contains two independent molecules, in each of which the pyrazine ring and dithiocarbazate unit are approximately co-planar, the r.m.s. deviations being 0.0304 and 0.0418 Å. The mean plane is oriented with respect to the benzene ring at 49.22 (4)° in one molecule and at 69.76 (7)° in the other. In the crystal, the molecules are linked to each other via intermolecular N—H⋯S hydrogen bonds, forming centrosymmetric supramolecular dimers. |
---|