Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate

The title compound, C(14)H(14)N(4)S(2), was obtained from a condensation reaction of benzyl dithio­carbazate and acetyl­pyrazine. The asymmetric unit contains two independent mol­ecules, in each of which the pyrazine ring and dithio­carbazate unit are approximately co-planar, the r.m.s. deviations b...

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Detalles Bibliográficos
Autores principales: Shan, Shang, Huang, Yan-Lan, Guo, Han-Qi, Li, Deng-Feng, Sun, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213547/
https://www.ncbi.nlm.nih.gov/pubmed/22091124
http://dx.doi.org/10.1107/S1600536811028480
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author Shan, Shang
Huang, Yan-Lan
Guo, Han-Qi
Li, Deng-Feng
Sun, Jian
author_facet Shan, Shang
Huang, Yan-Lan
Guo, Han-Qi
Li, Deng-Feng
Sun, Jian
author_sort Shan, Shang
collection PubMed
description The title compound, C(14)H(14)N(4)S(2), was obtained from a condensation reaction of benzyl dithio­carbazate and acetyl­pyrazine. The asymmetric unit contains two independent mol­ecules, in each of which the pyrazine ring and dithio­carbazate unit are approximately co-planar, the r.m.s. deviations being 0.0304 and 0.0418 Å. The mean plane is oriented with respect to the benzene ring at 49.22 (4)° in one mol­ecule and at 69.76 (7)° in the other. In the crystal, the mol­ecules are linked to each other via inter­molecular N—H⋯S hydrogen bonds, forming centrosymmetric supra­molecular dimers.
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spelling pubmed-32135472011-11-16 Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate Shan, Shang Huang, Yan-Lan Guo, Han-Qi Li, Deng-Feng Sun, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(14)N(4)S(2), was obtained from a condensation reaction of benzyl dithio­carbazate and acetyl­pyrazine. The asymmetric unit contains two independent mol­ecules, in each of which the pyrazine ring and dithio­carbazate unit are approximately co-planar, the r.m.s. deviations being 0.0304 and 0.0418 Å. The mean plane is oriented with respect to the benzene ring at 49.22 (4)° in one mol­ecule and at 69.76 (7)° in the other. In the crystal, the mol­ecules are linked to each other via inter­molecular N—H⋯S hydrogen bonds, forming centrosymmetric supra­molecular dimers. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213547/ /pubmed/22091124 http://dx.doi.org/10.1107/S1600536811028480 Text en © Shan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shan, Shang
Huang, Yan-Lan
Guo, Han-Qi
Li, Deng-Feng
Sun, Jian
Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate
title Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate
title_full Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate
title_fullStr Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate
title_full_unstemmed Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate
title_short Benzyl 3-[(E)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate
title_sort benzyl 3-[(e)-1-(pyrazin-2-yl)ethyl­idene]dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213547/
https://www.ncbi.nlm.nih.gov/pubmed/22091124
http://dx.doi.org/10.1107/S1600536811028480
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