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Benzyl 3-[(E)-2-nitro­benzyl­idene]dithio­carbazate

The title compound, C(15)H(13)N(3)O(2)S(2), was obtained from a condensation reaction of benzyl dithio­carbazate and 2-nitro­benzaldehyde. In the mol­ecule, the nearly planar dithio­carbazate fragment [r.m.s deviation = 0.0264 Å] is oriented at dihedral angles of 7.25 (17) and 74.09 (9)°with respect...

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Detalles Bibliográficos
Autores principales: Shan, Shang, Huang, Yan-Lan, Guo, Han-Qi, Li, Deng-Feng, Sun, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213549/
https://www.ncbi.nlm.nih.gov/pubmed/22091126
http://dx.doi.org/10.1107/S1600536811028686
Descripción
Sumario:The title compound, C(15)H(13)N(3)O(2)S(2), was obtained from a condensation reaction of benzyl dithio­carbazate and 2-nitro­benzaldehyde. In the mol­ecule, the nearly planar dithio­carbazate fragment [r.m.s deviation = 0.0264 Å] is oriented at dihedral angles of 7.25 (17) and 74.09 (9)°with respect to the two benzene rings. The nitro group is twisted by a dihedral angle of 22.4 (7)° to the attached benzene ring. The nitro­benzene ring and dithio­carbazate fragment are located on the opposite sides of the C=N bond, showing an E configuration. In the crystal, mol­ecules are linked via inter­molecular N—H⋯S hydrogen bonds, forming centrosymmetric supra­molecular dimers. Weak C—H⋯π inter­action is also observed in the crystal structure.