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4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol

In the title compound, C(25)H(32)Cl(2)N(2)O(2), there are two intra­molecular O—H⋯ N hydrogen-bonding inter­actions between the hy­droxy groups on the aromatic rings and the two N atoms of the heterocyclic group. The cyclo­hexane ring adopts a chair conformation and the imidazolidine unit to which i...

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Autores principales: Rivera, Augusto, Quiroga, Diego, Ríos-Motta, Jaime, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213571/
https://www.ncbi.nlm.nih.gov/pubmed/22091148
http://dx.doi.org/10.1107/S1600536811028960
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author Rivera, Augusto
Quiroga, Diego
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
author_facet Rivera, Augusto
Quiroga, Diego
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
author_sort Rivera, Augusto
collection PubMed
description In the title compound, C(25)H(32)Cl(2)N(2)O(2), there are two intra­molecular O—H⋯ N hydrogen-bonding inter­actions between the hy­droxy groups on the aromatic rings and the two N atoms of the heterocyclic group. The cyclo­hexane ring adopts a chair conformation and the imidazolidine unit to which it is fused has a twisted envelope conformation. The asymmetric unit comprises one half-mol­ecule which is completed by a twofold rotation axis. A C—H⋯O inter­action is observed in the crystal structure.
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spelling pubmed-32135712011-11-16 4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol Rivera, Augusto Quiroga, Diego Ríos-Motta, Jaime Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(32)Cl(2)N(2)O(2), there are two intra­molecular O—H⋯ N hydrogen-bonding inter­actions between the hy­droxy groups on the aromatic rings and the two N atoms of the heterocyclic group. The cyclo­hexane ring adopts a chair conformation and the imidazolidine unit to which it is fused has a twisted envelope conformation. The asymmetric unit comprises one half-mol­ecule which is completed by a twofold rotation axis. A C—H⋯O inter­action is observed in the crystal structure. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213571/ /pubmed/22091148 http://dx.doi.org/10.1107/S1600536811028960 Text en © Rivera et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rivera, Augusto
Quiroga, Diego
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol
title 4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol
title_full 4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol
title_fullStr 4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol
title_full_unstemmed 4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol
title_short 4,4′-Dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3aR,7aR/3aS,7aS)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol
title_sort 4,4′-dichloro-3,3′,5,5′-tetra­methyl-2,2′-[(3ar,7ar/3as,7as)-2,3,3a,4,5,6,7,7a-octa­hydro-1h-1,3-benzimidazole-1,3-di­yl)bis­(methyl­ene)]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213571/
https://www.ncbi.nlm.nih.gov/pubmed/22091148
http://dx.doi.org/10.1107/S1600536811028960
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