N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide

In the title mol­ecule, C(8)H(10)N(5)O(2)S, the amino­(azido)­methyl and p-toluene­sulfonyl moieties are inclined almost at right angles with respect to each other, making a dihedral angle of 83.49 (6)°. An intra­molecular N—H⋯O hydrogen bond gives rise to the formation of six-membered ring with gra...

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Detalles Bibliográficos
Autores principales: Mahmood, Ayyaz, Khan, Islam Ullah, Arshad, Muhammad Nadeem, Ahmed, Jamil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213580/
https://www.ncbi.nlm.nih.gov/pubmed/22091157
http://dx.doi.org/10.1107/S1600536811026973
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author Mahmood, Ayyaz
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Ahmed, Jamil
author_facet Mahmood, Ayyaz
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Ahmed, Jamil
author_sort Mahmood, Ayyaz
collection PubMed
description In the title mol­ecule, C(8)H(10)N(5)O(2)S, the amino­(azido)­methyl and p-toluene­sulfonyl moieties are inclined almost at right angles with respect to each other, making a dihedral angle of 83.49 (6)°. An intra­molecular N—H⋯O hydrogen bond gives rise to the formation of six-membered ring with graph-set motif S(6). In the crystal, inter­molecular N—H⋯O hydrogen bonding is responsible for the formation of dimers about inversion centers, which are linked through another N—H⋯O inter­action along the b axis.
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spelling pubmed-32135802011-11-16 N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide Mahmood, Ayyaz Khan, Islam Ullah Arshad, Muhammad Nadeem Ahmed, Jamil Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(8)H(10)N(5)O(2)S, the amino­(azido)­methyl and p-toluene­sulfonyl moieties are inclined almost at right angles with respect to each other, making a dihedral angle of 83.49 (6)°. An intra­molecular N—H⋯O hydrogen bond gives rise to the formation of six-membered ring with graph-set motif S(6). In the crystal, inter­molecular N—H⋯O hydrogen bonding is responsible for the formation of dimers about inversion centers, which are linked through another N—H⋯O inter­action along the b axis. International Union of Crystallography 2011-07-23 /pmc/articles/PMC3213580/ /pubmed/22091157 http://dx.doi.org/10.1107/S1600536811026973 Text en © Mahmood et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mahmood, Ayyaz
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Ahmed, Jamil
N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide
title N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide
title_full N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide
title_fullStr N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide
title_full_unstemmed N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide
title_short N-[Amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide
title_sort n-[amino­(azido)­meth­ylidene]-4-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213580/
https://www.ncbi.nlm.nih.gov/pubmed/22091157
http://dx.doi.org/10.1107/S1600536811026973
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