(1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide

The title compound, [1-(CH(3))(3)NCH(2)-1,2-C(2)B(10)H(11)](+)·I(−) or C(6)H(22)B(10)N(+)·I(−), was obtained by the reaction of (1,2-dicarba-closo-dodeca­boran­yl)dimethyl­methanamine with methyl iodide. The asymmetric unit contains two iodide anions and two (o-carboran­yl)tetra­methyl­ammonium cati...

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Detalles Bibliográficos
Autores principales: Lee, Jong-Dae, Han, Won-Sik, Suh, Il-Hwan, Kang, Sang Ook
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213586/
https://www.ncbi.nlm.nih.gov/pubmed/22091163
http://dx.doi.org/10.1107/S160053681102928X
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author Lee, Jong-Dae
Han, Won-Sik
Suh, Il-Hwan
Kang, Sang Ook
author_facet Lee, Jong-Dae
Han, Won-Sik
Suh, Il-Hwan
Kang, Sang Ook
author_sort Lee, Jong-Dae
collection PubMed
description The title compound, [1-(CH(3))(3)NCH(2)-1,2-C(2)B(10)H(11)](+)·I(−) or C(6)H(22)B(10)N(+)·I(−), was obtained by the reaction of (1,2-dicarba-closo-dodeca­boran­yl)dimethyl­methanamine with methyl iodide. The asymmetric unit contains two iodide anions and two (o-carboran­yl)tetra­methyl­ammonium cations. The bond lengths and angles in the carborane cage are within normal ranges, but the N—C(methyl­ene)—C(cage) angle is very large [120.2 (2)°] because of repulsion between the carborane and tetra­methyl­ammonium units. In the crystal, ions are linked through C—H⋯I hydrogen bonds.
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spelling pubmed-32135862011-11-16 (1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide Lee, Jong-Dae Han, Won-Sik Suh, Il-Hwan Kang, Sang Ook Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, [1-(CH(3))(3)NCH(2)-1,2-C(2)B(10)H(11)](+)·I(−) or C(6)H(22)B(10)N(+)·I(−), was obtained by the reaction of (1,2-dicarba-closo-dodeca­boran­yl)dimethyl­methanamine with methyl iodide. The asymmetric unit contains two iodide anions and two (o-carboran­yl)tetra­methyl­ammonium cations. The bond lengths and angles in the carborane cage are within normal ranges, but the N—C(methyl­ene)—C(cage) angle is very large [120.2 (2)°] because of repulsion between the carborane and tetra­methyl­ammonium units. In the crystal, ions are linked through C—H⋯I hydrogen bonds. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3213586/ /pubmed/22091163 http://dx.doi.org/10.1107/S160053681102928X Text en © Lee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lee, Jong-Dae
Han, Won-Sik
Suh, Il-Hwan
Kang, Sang Ook
(1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide
title (1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide
title_full (1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide
title_fullStr (1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide
title_full_unstemmed (1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide
title_short (1,2-Dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide
title_sort (1,2-dicarba-closo-dodeca­boran­yl)trimethyl­methanaminium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213586/
https://www.ncbi.nlm.nih.gov/pubmed/22091163
http://dx.doi.org/10.1107/S160053681102928X
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