Cargando…
(2Z)-3-(4-Chloroanilino)-1-(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)but-2-en-1-one
With the exception of the terminal benzene rings, the atoms in the title compound, C(20)H(18)ClN(3)O(2), are approximately coplanar (r.m.s. deviation = 0.0495 Å). The benzene/chlorobenzene rings form dihedral angles of 3.02 (4) and 41.59 (5)°, respectively, with this plane. The hydroxy, amino and...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213593/ https://www.ncbi.nlm.nih.gov/pubmed/22091170 http://dx.doi.org/10.1107/S1600536811029473 |
Sumario: | With the exception of the terminal benzene rings, the atoms in the title compound, C(20)H(18)ClN(3)O(2), are approximately coplanar (r.m.s. deviation = 0.0495 Å). The benzene/chlorobenzene rings form dihedral angles of 3.02 (4) and 41.59 (5)°, respectively, with this plane. The hydroxy, amino and carbonyl groups all lie to the same side of the molecule, enabling the formation of intramolecular O—H⋯O and N—H⋯O hydrogen bonds that close S(6) rings. The configuration about the 2-butene bond is Z. Supramolecular chains mediated by C—H⋯Cl interactions and aligned along the c axis are found in the crystal packing. These assemble into layers that are connected by weak π–π interactions between centrosymmetrically related chlorobenzene rings [3.8156 (9) Å]. |
---|